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Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XIX. Synthesis of N-(4-Allyloxy-2,3,5,6-tetrafluorophenyl)salicylaldimines and Their Complexes with Titanium(IV) Dichloride

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Abstract

The reaction of 3- and 3,5-substituted salicylic aldehydes containing tert-butyl or 2-phenylpropan-2-yl groups in position 3 with 4-allyloxy-2,3,5,6-tetrafluoroaniline in toluene in the presence of para-toluenesulfonic acid was used to obtain a series of corresponding (N-aryl)salicylaldimines, which form complexes of titanium(IV) dichloride L2TiCl2 upon interaction with TiCl2(OPr-i)2.

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ACKNOWLEDGMENTS

The authors are grateful to the Chemical Research Center of the Siberian Branch of the Russian Academy of Sciences for obtaining of spectral and analytical data.

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the governmental task of the N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences.

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Authors and Affiliations

  1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    I. V. Oleynik & I. I. Oleynik

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  1. I. V. Oleynik
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  2. I. I. Oleynik
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Correspondence to I. I. Oleynik.

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The authors declare no conflict of interest.

Additional information

For communication XVIII, see [1].

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Oleynik, I.V., Oleynik, I.I. Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XIX. Synthesis of N-(4-Allyloxy-2,3,5,6-tetrafluorophenyl)salicylaldimines and Their Complexes with Titanium(IV) Dichloride. Russ J Gen Chem 92, 1457–1466 (2022). https://doi.org/10.1134/S1070363222080138

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