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Synthesis and Structure of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5)

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Abstract

Bismuth compounds Ph3Bi[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5) were synthesized by the reaction of triphenylbismuth with a carboxylic acid and tert-butyl hydroperoxide (1 : 2 : 1 mol.) in diethyl ether. Structural features of these compounds were determined by the single crystal X-ray analysis method. Bismuth atoms in triphenylbismuth dicarboxylates have distorted trigonal-bipyramidal coordination with oxygen atoms in axial positions. The presence of intramolecular contacts Bi···O(=C) [2.833(8)–3.136(9) Å] causes an increase in one of CBiC bond angles to 151.07(15)°, 142.0(3)°, 138.53(14)°, respectively, due to a decrease in the other two angles.

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & L. V. Koscheeva

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. L. V. Koscheeva
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Correspondence to V. V. Sharutin.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 5, pp. 758–762 https://doi.org/10.31857/S0044460X21050139.

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Sharutin, V.V., Sharutina, O.K. & Koscheeva, L.V. Synthesis and Structure of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5). Russ J Gen Chem 91, 840–843 (2021). https://doi.org/10.1134/S1070363221050133

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