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Synthesis and Structures of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = C6H4OMe-2, C6H3(NO2)2-3,5, and C≡CPh)

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Abstract

Compounds Ph3Bi[OC(O)R]2 (R = C6H4OMe-2 (I), C6H3(NO2)2-3,5 (II), and C≡CPh (III)) have been synthesized from triphenylbismuth, carboxylic acid, and tert-butyl hydroperoxide (1 : 2 : 1 mol) and their structural features have been established by X-ray diffraction. Bismuth atoms in I–III have distorted trigonal-bipyramidal coordination with carboxylate ligands in axial positions. The OBiO angles are 172.95(13)°−175.6(2)°, the Bi–C and Bi–O distances are 2.176(6)–2.251(5) and 2.280(4)–2.310(3) Å, respectively. The presence of intramolecular contacts Bi⋅⋅⋅O(=C) (2.759(6)–2.982(7) Å) in molecules I–III causes an increase in one bond angle CBiC (up to 154.4(3)°, 140.2(2)°, 145.3(4)°, respectively) by decreasing the other two.

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  1. South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & L. V. Koshcheeva

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. L. V. Koshcheeva
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Correspondence to V. V. Sharutin.

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Sharutin, V.V., Sharutina, O.K. & Koshcheeva, L.V. Synthesis and Structures of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = C6H4OMe-2, C6H3(NO2)2-3,5, and C≡CPh). Russ. J. Inorg. Chem. 66, 1488–1491 (2021). https://doi.org/10.1134/S0036023621100168

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