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Synthesis and Structures of Triphenylbismuth Bis[3-(2-Furyl)Acrylate] Ph3Bi[O2CCH=CH(C4H3O)]2 and Triphenylbismuth Di-meta-nitrocinnamate Ph3Bi(O2CCH=CH–С6H4NO2-m)2

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Abstract

Triphenylbismuth bis[3-(2-furyl)acrylate] Ph3Bi[O2CCH=CH(C4H3O)]2 and triphenylbismuth di-meta-nitrocinnamate Ph3Bi(O2CCH=CH–C6H4NO2-m)2 were synthesized and studied by X-ray diffraction. The crystal structures (sp. gr. P1, Z = 2; sp. gr. P21, Z = 2, respectively) contain one and two tetrahydrofuran solvent molecules, respectively, per bismuth complex. The bismuth atom has a trigonal-bipyramidal coordination geometry. Additional weak Bi···O interactions (2.748–2.835 Å) cause large angle distortions in the equatorial plane of the trigonal bipyramid.

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, 603950, Russia

    A. A. Gusakovskaya, O. S. Kalistratova, P. V. Andreev, A. V. Gushchin, N. V. Somov & E. V. Chuprunov

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  1. A. A. Gusakovskaya
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  2. O. S. Kalistratova
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  3. P. V. Andreev
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  4. A. V. Gushchin
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  5. N. V. Somov
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  6. E. V. Chuprunov
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Corresponding author

Correspondence to P. V. Andreev.

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Original Russian Text © A.A. Gusakovskaya, O.S. Kalistratova, P.V. Andreev, A.V. Gushchin, N.V. Somov, E.V. Chuprunov, 2018, published in Kristallografiya, 2018, Vol. 63, No. 2, pp. 203–207.

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Gusakovskaya, A.A., Kalistratova, O.S., Andreev, P.V. et al. Synthesis and Structures of Triphenylbismuth Bis[3-(2-Furyl)Acrylate] Ph3Bi[O2CCH=CH(C4H3O)]2 and Triphenylbismuth Di-meta-nitrocinnamate Ph3Bi(O2CCH=CH–С6H4NO2-m)2. Crystallogr. Rep. 63, 186–190 (2018). https://doi.org/10.1134/S1063774518020062

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  • DOI: https://doi.org/10.1134/S1063774518020062

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