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Preparation of Nanosized α-Fe2O3 Using Mechanical Activation

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Abstract

The processes occurring during the mechanical activation of a-Fe2O3 (hematite) in the presence of oleic acid in a centrifugal-planetary mill have been investigated. Mechanical activation for 10 h afforded hematite powder with particles size of 10–40 nm, as shown by means of X-ray diffraction analysis, FTIR spectroscopy, high-resolution transmission electron microscopy, and specific surface area measurements. Longer milling has led to mechanochemical transformation of hematite into Fe3O4 (magnetite).

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Funding

This study was financially supported by the Ministry of Science and Higher Education of Russian Federation (ID RFMEFI62117X0018). TEM studies were performed at the Center for Collective Usage “Materials Science and Diagnostics in Modern Technology”, Ioffe Institute, St. Petersburg, Russia.

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Authors and Affiliations

  1. Tananaev Institute of Chemistry, Federal Research Center “Kola Science Center of the Russian Academy of Sciences,”, Apatity, 184209, Russia

    A. M. Kalinkin, Yu. V. Kuz’mich & O. A. Zalkind

  2. Ioffe Institute, St. Petersburg, 194021, Russia

    V. N. Nevedomskii

Authors
  1. A. M. Kalinkin
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  2. Yu. V. Kuz’mich
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  3. O. A. Zalkind
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  4. V. N. Nevedomskii
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Correspondence to A. M. Kalinkin.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 12, pp. 1949–1954.

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Kalinkin, A.M., Kuz’mich, Y.V., Zalkind, O.A. et al. Preparation of Nanosized α-Fe2O3 Using Mechanical Activation. Russ J Gen Chem 89, 2453–2457 (2019). https://doi.org/10.1134/S107036321912020X

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  • DOI: https://doi.org/10.1134/S107036321912020X

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