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Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes

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Abstract

The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl was studied. The chemisorption of gold from the solution forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido complex comprising three isomeric gold cations and an unsymmetrical hexachlorodimercurate anion. The structural organization and thermal behavior of the resulting compounds was studied.

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References

  1. World Health Organization (WHO), 1991; Environmental Health Criteria 118, inorganic mercury, Geneva.

  2. Bernhoft, R.A., J. Environ. Publ. Health, 2012, vol. 2012. Article ID 460508. doi https://doi.org/10.1155/2012/460508

  3. Advances in Environmental Chemistry and Toxicology of Mercury, Liu, G., Y. Cai, Y., and O’Driscoll, N., Eds., Hoboken: Wiley, 2012.

    Google Scholar 

  4. Byr’ko, V.M., Ditiokarbamaty (Dithiocarbamates), Moscow: Nauka, 1984.

    Google Scholar 

  5. Green, M., Prince, P., Gardner, M., and Steed, J., Adv. Mater. 2004, vol. 16, no. 12, p. 994. doi https://doi.org/10.1002/adma.200306407

    Article  CAS  Google Scholar 

  6. Onwudiwe, D.C. and Ajibade, P.A., Mater. Lett. 2011, vol. 65, nos. 21–22, p. 3258. doi https://doi.org/10.1016/j.matlet.2011.07.012

  7. Srinivasan, N., Thirumaran, S., and Ciattini, S., J. Mol. Struct., 2014, vol. 1076, p. 382. doi https://doi.org/10.1016/j.molstruc.2014.07.083

    Article  CAS  Google Scholar 

  8. Srinivasan, N., Thirumaran, S., and Ciattini, S., RSC Adv., 2014, vol. 4, no. 44, p. 22971. doi https://doi.org/10.1039/C4RA01913J

    Article  CAS  Google Scholar 

  9. Dar, S.H., Thirumaran, S., and Selvanayagam, S., Polyhedron 2015, vol. 96, p. 16. doi https://doi.org/10.1016/j.poly.2015.04.020

    Article  CAS  Google Scholar 

  10. Loseva, O.V., Rodina, T.A., Smolentsev, A.I., and Ivanov, A.V., Russ. J. Coord. Chem. 2016, vol. 42, no. 11, p. 719. doi https://doi.org/10.1134/S1070328416110063

    Article  CAS  Google Scholar 

  11. Loseva, O.V., Rodina, T.A., Smolentsev, A.I., and Ivanov, A.V., Polyhedron 2017, vol. 134, p. 238. doi https://doi.org/10.1016/j.poly.2017.06.021

    Article  CAS  Google Scholar 

  12. Cox, M.J. and Tiekink, E.R.T., Z. Kristallogr., 1999, vol. 214, no. 9, p. 571. doi https://doi.org/10.1524/zkri.1999.214.9.571

    CAS  Google Scholar 

  13. Cox, M.J. and Tiekink, E.R.T., Main Group Met. Chem. 2000, vol. 23, no. 12, p. 793. doi https://doi.org/10.1515/MGMC.2000.23.12.793

    Article  CAS  Google Scholar 

  14. Ivanov, A.V., Korneeva, E.V., Bukvetskii, B.V., Goryan, A.S., Antzutkin, O.N., and Forsling, W., Russ. J. Coord. Chem. 2008, vol. 34, no. 1, p. 59. doi https://doi.org/10.1007/s11173-008-1010-3

    Article  CAS  Google Scholar 

  15. Altaf, M., Stoeckli-Evans, H., Batool, S.S., Isab, A.A., Ahmad, S., Saleem, M., Awan, S.A., and Shaheen, M.A., J. Coord. Chem., 2010, vol. 63, no.7, p. 1176. doi https://doi.org/10.1080/00958971003759085

  16. Onwudiwe, D.C. and Ajibade, P.A., J. Chem. Crystallogr., 2011, vol. 41, no.7, p. 980. doi https://doi.org/10.1007/s10870-011-0029-3

  17. Onwudiwe, D.C. and Ajibade, P.A., Int. J. Mol. Sci. 2011, vol. 12, no.3, p. 1964. doi https://doi.org/10.3390/ijms12031964

  18. Yadav, M.K., Rajput, G., Gupta, A.N., Kumar, V., Drew, M.G.B., and Singh, N., Inorg. Chim. Acta 2014, vol. 421, p. 210. doi https://doi.org/10.1016/j.ica.2014.05.031

    Article  CAS  Google Scholar 

  19. Rajput, G., Yadav, M.K., Thakur, T.S., Drew, M.G.B., and Singh, N., Polyhedron 2014, vol. 69, p. 225. doi https://doi.org/10.1016/j.poly.2013.12.005

    Article  CAS  Google Scholar 

  20. Rodina, T.A., Ivanov, A.V., Gerasimenko, A.V., Loseva, O.V., Antzutkin, O.N., and Sergienko, V.I., Polyhedron 2012, vol. 40, no.1, p. 53. doi https://doi.org/10.1016/j.poly.2012.03.043

  21. Winter, M., WebElements Periodic Table of the Elements. http://www.webelements.com.

  22. Addison, A.W., Rao, T.N., Reedijk, J., van Rijn, J., and Verschoor, G.C., J. Chem. Soc. Dalton Trans., 1984, no. 7, p. 1349. doi https://doi.org/10.1039/DT9840001349

    Article  Google Scholar 

  23. Alcock, N.W., Adv. Inorg. Chem. Radiochem. 1972, vol. 15, no.1, p. 1. doi https://doi.org/10.1016/S0065-2792(08)60016-3

  24. Akamova, L.V., Tomilin, O.B., Terekhin, I.I., Stankevich, I.V., and Chistyakov, A.L., J. Struct. Chem., 1998, vol. 39, no.1, p. 21. doi https://doi.org/10.1007/BF02873820

  25. Exarchos, G., Robinson, S.D., and Steed, J.W., Polyhedron 2001, vol. 20, nos. 24–25, p. 2951. doi 10.1016.S0277-5387(01)00885-3

  26. Elwej, R., Hannachi, N., Chaabane, I., Oueslati, A., and Hlel, F., Inorg. Chim. Acta 2013, vol. 406, p. 10. doi https://doi.org/10.1016/j.ica.2013.06.046

    Article  CAS  Google Scholar 

  27. Oleinik, S.P., Matyna, L.I., Chistyakov, Yu.D., Pekarev, A.I., and Varlamov, I.V., Dokl. Akad. Nauk 1989, vol. 307, no. 6, p. 1411.

    CAS  Google Scholar 

  28. Lalia-Kantouri, M., Christofides, A., and Manoussakis, G.E., J. Thermal Anal. Calorim., 1984, vol. 29, no. 2, p. 279.

    Article  CAS  Google Scholar 

  29. Lalia-Kantouri, M. and Manoussakis, G.E., J. Thermal Anal. Calorim., 1984, vol. 29, no. 5, p. 1151.

    Article  CAS  Google Scholar 

  30. Ivanov, A.V., Loseva, O.V., Rodina, T.A., Gerasimenko, A.V., and Novikova, E.V., Russ. J. Coord. Chem. 2016, vol. 42, no. 2, p. 104. doi https://doi.org/10.1134/S1070328416020032

    Article  CAS  Google Scholar 

  31. Lidin, R.A., Andreeva, L.L., and Molochko, V.A., Konstanty neorganicheskikh veshchestv: spravochnik (Constants of Inorganic Substances: Handbook), Moscow: Drofa 2008, p. 180.

    Google Scholar 

  32. Pines, A., Gibby, M.G., and Waugh, J.S., J. Chem. Phys., 1972, vol. 56, no. 4, p. 1776. doi https://doi.org/10.1063/1.1677439

    Article  CAS  Google Scholar 

  33. Bruker, APEX2 (version 1.08), SAINT (version 7.03), SADABS (version 2.11), SHELXTL (version 6.12). Madison, Wis: Bruker AXS, 2004.

  34. Ivanov, A.V. and Antzutkin, O.N., Top. Curr. Chem. 2005, vol. 246, p. 271. doi https://doi.org/10.1007/b98653

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far-East Branch, Russian Academy of Sciences, per. Relochnyi 1, Blagoveshchensk, 675000, Russia

    O. V. Loseva & A. V. Ivanov

  2. Amur State University, Blagoveshchensk, Russia

    T. A. Rodina

  3. Luleå University of Technology, Luleå, Sweden

    O. N. Antzutkin

  4. University of Warwick, Coventry, United Kingdom

    O. N. Antzutkin

Authors
  1. O. V. Loseva
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  2. T. A. Rodina
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  3. O. N. Antzutkin
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  4. A. V. Ivanov
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Correspondence to A. V. Ivanov.

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Original Russian Text © O.V. Loseva, T.A. Rodina, O.N. Antzutkin, A.V. Ivanov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 12, pp. 2024–2033.

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Loseva, O.V., Rodina, T.A., Antzutkin, O.N. et al. Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes. Russ J Gen Chem 88, 2540–2549 (2018). https://doi.org/10.1134/S1070363218120149

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  • DOI: https://doi.org/10.1134/S1070363218120149

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