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Conductometric study of complex formation between benzylbisthiosemicarbazone and metal cations in acetonitrile, dimethylformamide, and their binary mixtures

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An Erratum to this article was published on 01 March 2015

Abstract

We report on conductometric study of complexation between benzylbisthiosemicarbazone [(2E,2′E)-2,2′-(1,2-diphenylethane-1,2-diylidene)bis(hydrazine-1-carbothioamide)] with Zn2+, Cr3+, Co2+, and Ni2+ cations at different temperatures in acetonitrile-dimethylformamide binary solvents of varied composition. The equilibrium constant and standard thermodynamic parameters (Δc H 0 and Δc S 0) of the complexes formation have been determined and found to be dependent on the binary solvent composition, the metal ion nature, and temperature.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

    Hamideh Sharifi Noghabi, Gholam Hossein Rounaghi & Mohammad Hossein ArbabZavar

  2. Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Javad Ebrahimi

Authors
  1. Hamideh Sharifi Noghabi
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  2. Gholam Hossein Rounaghi
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  3. Mohammad Hossein ArbabZavar
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  4. Javad Ebrahimi
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Correspondence to Hamideh Sharifi Noghabi.

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Noghabi, H.S., Rounaghi, G.H., ArbabZavar, M.H. et al. Conductometric study of complex formation between benzylbisthiosemicarbazone and metal cations in acetonitrile, dimethylformamide, and their binary mixtures. Russ J Gen Chem 84, 1429–1433 (2014). https://doi.org/10.1134/S1070363214070317

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  • DOI: https://doi.org/10.1134/S1070363214070317

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