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A thermodynamic study of complexation process between N,N′-dipyridoxylidene(1,4-butanediamine) and Cd2+ in some binary mixed solvents using conductometry

  • Colloid Chemistry and Electrochemistry
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Abstract

Complexation of the Cd2+ ion with N,N′-dipyridoxylidene(1,4-butanediamine) Schiff base was studied in pure solvents including acetonitrile (AN), ethanol (EtOH), methanol (MeOH), tetrahydrofuran (THF), dimethylformamide (DMF), water (H2O), and various binary solvent mixtures of acetonitrile–ethanol (AN–EtOH), acetonitrile–methanol (AN–MeOH), acetonitrile–tetrahydrofuran (AN–THF), acetonitrile–dimethylformamide (AN–DMF), and acetonitrile–water (AN–H2O) systems at different temperatures using the conductometric method. The conductance data show that the stoichiometry of complex is 1: 1 [ML] in all solvent systems. A non-linear behavior was observed for changes of log K f of [Cd(N,N′-dipyridoxylidene(1,4-butanediamine)] complex versus the composition of the binary mixed solvents, which was explained in terms of solvent–solvent interactions. The results show that the thermodynamics of complexation reaction is affected by the nature and composition of the mixed solvents.

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Authors and Affiliations

  1. Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Sonia Ebrahimpoor, Razieh Sanavi Khoshnood & S. Ali Beyramabadi

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  1. Sonia Ebrahimpoor
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  2. Razieh Sanavi Khoshnood
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  3. S. Ali Beyramabadi
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Correspondence to Razieh Sanavi Khoshnood.

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Ebrahimpoor, S., Khoshnood, R.S. & Beyramabadi, S.A. A thermodynamic study of complexation process between N,N′-dipyridoxylidene(1,4-butanediamine) and Cd2+ in some binary mixed solvents using conductometry. Russ. J. Phys. Chem. 90, 2646–2653 (2016). https://doi.org/10.1134/S0036024416130185

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