Abstract
Thermochemical parameters, like standard enthalpy of formation (ΔH 0298 ), enthalpy increment from 0 to 298 K (H 0298 - H 00 ), standard heat capacity (C 0p298 ) and its temperature dependence [Cp(T)], and entropy (S 0298 ), were calculated for the gaseous methoxy derivatives formed from polychlotinated biphenyl (PCB) congeners. Thermodynamic modeling and the HSC software were used to evaluate the reactivity of PCB congeners toward sodium methoxide in DMSO, and the calculation results were compared with experimental data.
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Original Russian Text © T.V. Kulikova, A.V. Maiorova, K.Yu. Shunyaev, T.I. Gorbunova, V.I. Saloutin, O.N. Chupakhin, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 5, pp. 754–762.
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Kulikova, T.V., Maiorova, A.V., Shunyaev, K.Y. et al. Thermodynamic modeling of the reaction of polychlorinated biphenyls with sodium methoxide. Russ J Gen Chem 83, 893–900 (2013). https://doi.org/10.1134/S1070363213050034
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DOI: https://doi.org/10.1134/S1070363213050034