Abstract
The relation between the position of the charge transfer band of molecular complexes formed by p-chloranil with benzene derivatives and ionization potentials of the donor molecule was analyzed. Electronic absorption spectra of p-chloranil complexes with donor molecules possessing degenerate molecular orbitals were examined. Unlike complexes with other acceptors, such as 1,3,5-trinitrobenzene and 1,3-dinitrobenzenea, molecular complexes of p-chloranil with analogous donors were classed within a single group.
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Original Russian Text © B.S. Pryalkin, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 2, pp. 249–256.
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Pryalkin, B.S. Molecular complexes of quinones: I. π-π complexes of p-chloranil with benzene and its derivatives. Russ J Gen Chem 83, 303–310 (2013). https://doi.org/10.1134/S1070363213020126
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DOI: https://doi.org/10.1134/S1070363213020126