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11-R-dibenzo[b,e][1,4]diazepin-1-ones, the chemosensors for transition metal cations

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Abstract

A series of 11-R-dibenzo[b,e][1,4]diazepin-1-ones was synthesized. The luminescence, complex formation, and redox properties of these compounds were investigated. The 11-(anthracen-9-yl)-3,3-dimethyl-2,3,4,5,10,11-hexahydro-1H-dibenzo[b,e][1,4]diazepin-1-one was found to be an effective and selective fluorescent chemosensor for Cd2+ cations.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, ul. Stachki 194/2, Rostov-on-Don, 344090, Russia

    I. E. Tolpygin, N. V. Mikhailenko, U. V. Revinsky, V. A. Bren’ & V. I. Minkin

  2. Southern Research Center, Russian Academy of Sciences, ul. Chekhova, 4, Rostov-on-Don, 344010, Russia

    A. A. Bumber, E. N. Shepelenko, A. D. Dubonosov & V. I. Minkin

Authors
  1. I. E. Tolpygin
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  2. N. V. Mikhailenko
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  3. A. A. Bumber
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  4. E. N. Shepelenko
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  5. U. V. Revinsky
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  6. A. D. Dubonosov
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  7. V. A. Bren’
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  8. V. I. Minkin
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Correspondence to I. E. Tolpygin.

Additional information

Original Russian Text © I.E. Tolpygin, N.V. Mikhailenko, A.A. Bumber, E.N. Shepelenko, U.V. Revinsky, A.D. Dubonosov, V.A. Bren’, V.I. Minkin, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 7, pp. 1141–1147.

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Tolpygin, I.E., Mikhailenko, N.V., Bumber, A.A. et al. 11-R-dibenzo[b,e][1,4]diazepin-1-ones, the chemosensors for transition metal cations. Russ J Gen Chem 82, 1243–1249 (2012). https://doi.org/10.1134/S1070363212070109

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  • DOI: https://doi.org/10.1134/S1070363212070109

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