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Three metal complexes based on tetrazolyl ligands: Hydrothermal syntheses, crystal structures, and fluorescence properties

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Abstract

Three new complexes based on 1-tetrazole-4-imidazole-benzene (Tibz), namely, [Cd(Tibz)2(H2O)2] n (I), [Mn(Tibz)2(H2O)4] · 2H2O (II) and [Co(Tibz)2(H2O)4] · 2H2O (III) have been synthesized through hydrothermal method and structurally characterized by element analyses, IR spectroscopy and single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1443867 (I), 1443868 (II), 1443869 (III)). Single-crystal X-ray diffraction reveals that complex I is a 1D double-chain architecture, II and III are both mononuclear complexes. The results of single-crystal X-ray diffraction analyses indicate that the hydrogen bond and π··· π stacking exist in the complexes, which make great contribution to the stabilities of complexes I–III. The fluorescent properties of these complexes have also been studied in the solid state at room temperature.

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, 450001, P.R. China

    F. Wang, C. J. Wu, X. X. Liang, J. P. Li & Z. Y. Liu

  2. Department of Chemistry, Henan Institute of Education, Zhengzhou, Henan, 450014, P.R. China

    F. Wang

  3. Zhengzhou Foreign Language High School, Zhengzhou, Henan, 450001, P.R. China

    M. Y. Li

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  1. F. Wang
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  2. C. J. Wu
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  3. X. X. Liang
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  4. M. Y. Li
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  5. J. P. Li
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  6. Z. Y. Liu
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Correspondence to J. P. Li.

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Wang, F., Wu, C.J., Liang, X.X. et al. Three metal complexes based on tetrazolyl ligands: Hydrothermal syntheses, crystal structures, and fluorescence properties. Russ J Coord Chem 42, 789–796 (2016). https://doi.org/10.1134/S1070328416120071

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  • DOI: https://doi.org/10.1134/S1070328416120071

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