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SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENCE PROPERTIES OF A Cd2+ COMPLEX OF A PYRIDINE-BIS-BENZIMIDAZOLE LIGAND

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Abstract

In this work, a seven-coordinate Cd2+ complex of a tridentate pyridine-bis-benzimidazole ligand (L1) was prepared and structure of the complex was characterized by FTIR and single crystal XRD studies. The X-ray crystallographic data revealed that Cd2+ binds to a tridentate benzimidazole ligand and two nitrate anions (\(\text{NO}_{3}^{-}\)) (bidentate fashion). The crystal structure of the Cd2+ complex was stabilised by π–π stacking and C–H⋯ONO2 interactions. The complex showed intense blue emission in the solutions in the range of 350-500 nm.

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Authors and Affiliations

  1. Department of Property Protection and Safety, Elbistan Vocational School, Kahramanmaras Istiklal University, Kahramanmaras, Turkey

    A. Köse

  2. Department of Materials Science and Engineering, Kahramanmaras Sutcu Imam University, Kahramanmaraş, Turkey

    M. Bal

Authors
  1. A. Köse
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  2. M. Bal
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Correspondence to A. Köse or M. Bal.

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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 12, 103106.https://doi.org/10.26902/JSC_id103106

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Köse, A., Bal, M. SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENCE PROPERTIES OF A Cd2+ COMPLEX OF A PYRIDINE-BIS-BENZIMIDAZOLE LIGAND. J Struct Chem 63, 1981–1987 (2022). https://doi.org/10.1134/S0022476622120095

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