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Solution-solid phase equilibrium in the systems MgBr2-NR4Br-H2O at 25°C (R = Me, Et, Bu)

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Abstract

Solubility in the ternary systems MgBr2-NR4Br-H2O (R = Me, Et, Bu) at 25°C was determined by the isothermal saturation method. A comparative analysis of phase diagrams was fulfilled. The results obtained were interpreted in the context of competition between hydration and association processes in water-salt systems. The structure of double salts NMe4Br·MgBr2·6H2O and NEt4Br·MgBr2·8H2O was determined, and the possibility for predicting compositions of crystallizing double salts on the basis of crystallographic characteristics of ions was analyzed.

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References

  1. Kessler, Yu.M. and Zaitsev, A.L., Solvofobnye effekty (Solvophobic Effects), Leningrad: Khimiya, 1989.

    Google Scholar 

  2. Gusev, I.M. and Skripkin, M.J., Zh. Prikl. Khim., 2009, vol. 82, no. 2, p. 229.

    Google Scholar 

  3. Bogoyavlenskii, P.S. and Fedunyak, I.F., Zh. Neorg. Khim., 1972, vol. 17, no. 1, p. 296.

    Google Scholar 

  4. Blidin, V.D., Zh. Obshch. Khim., 1947, vol. 1, no. 9, p. 1951.

    Google Scholar 

  5. Balarew, Chr., Christov, Ch., Valyashko, V.I., and Petrenko, I.S., J. Solution Chem., 1993, vol. 22, no. 2, p. 173.

    Article  CAS  Google Scholar 

  6. Yakimov, M.A., Problemy sovremennoi khimii koordinatsionnykh soedinenii (Problems of Modern Chemistry of Coordination Compounds), 1966, no. 1, p. 136.

  7. Wen, W.-Y., J. Solution Chem., 1973, vol. 2, nos. 2–3, p. 253.

    Article  CAS  Google Scholar 

  8. Wolthuis, A.J., Huisksmp, W.J., and De Jongh, L.J., Physica B, 1986, vol. 142, p. 301.

    Article  CAS  Google Scholar 

  9. Waizumi, K., Masuda, H., Ohtaki, H., Skripkin, M.Yu., and Burkov, K.A., American Mineralogist, 1991, vol. 76, no. 10, p. 1884.

    CAS  Google Scholar 

  10. Balarew, C. and Tepavitcharova, S., Monatsh. Chem., 2003, vol. 134, no. 5, p. 721.

    CAS  Google Scholar 

  11. Voskresenskaya, I.K. and Yanat’eva, O.K., Izv. Akad. Nauk SSSR, Ser. Khim., 1937, no. 1, p. 97.

  12. Chernykh, L.V., Bulgakova, T.N., Skripkin, M.Yu., and Burkov, K.A., Zh. Prikl. Khim., 1998, vol. 71, no. 9, p. 1425.

    CAS  Google Scholar 

  13. Altomare, A., Burle, M.C., Camalli, N., Cascarano, G., Giacovazzo, G., Guagliardi, A., Moliterni, A.G.G., Polidori, G., and Spagna, R., SIR-97. A Program for Automatic Solution and Refinment of Crystal Structure, Trieste, Italy.

  14. Sheldrick, G.M., SHELXL 97, University of Gottingen, Germany.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198904, Russia

    I. M. Gusev, M. Yu. Skripkin, K. K. Spektor & G. L. Starova

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  1. I. M. Gusev
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  2. M. Yu. Skripkin
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  3. K. K. Spektor
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  4. G. L. Starova
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Correspondence to I. M. Gusev.

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Original Russian Text © I.M. Gusev, M.Yu. Skripkin, K.K. Spektor, G.L. Starova, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 4, pp. 529–533.

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Gusev, I.M., Skripkin, M.Y., Spektor, K.K. et al. Solution-solid phase equilibrium in the systems MgBr2-NR4Br-H2O at 25°C (R = Me, Et, Bu). Russ J Gen Chem 81, 623–627 (2011). https://doi.org/10.1134/S1070363211040013

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  • DOI: https://doi.org/10.1134/S1070363211040013

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