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Biphilic properties of substituted triphenylphosphoranylideneacetonitriles bearing 4,5-Di(arylsulfonyl)-1,3-thiazol-2-yl fragments at the ylide center

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Abstract

Phosphonium ylides stabilized by nitrile and 4,5-di(arylsulfonyl)-1,3-thiazol-2-yl fragments show biphilic reactivity. They react with aromatic aldehydes upon heating revealing a noticeable activity of ylide center and are condensed with typical nucleophiles at C4 center of the thiazole ring with the elimination of arylsulfonyl group under mild conditions. New 1,3-thiazole derivatives were obtained whose structures were proved by chemical, spectal and X-ray structural investigations.

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Authors and Affiliations

  1. Institute of Bioorganic and Petroleum Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 1, Kiev-94, 02660, Ukraine

    K. V. Turov & B. S. Drach

  2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    E. B. Rusanov

Authors
  1. K. V. Turov
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  2. E. B. Rusanov
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  3. B. S. Drach
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Correspondence to B. S. Drach.

Additional information

Original Russian Text © K.V. Turov, E.B. Rusanov, B.S. Drach, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 7, pp. 1110–1115.

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Turov, K.V., Rusanov, E.B. & Drach, B.S. Biphilic properties of substituted triphenylphosphoranylideneacetonitriles bearing 4,5-Di(arylsulfonyl)-1,3-thiazol-2-yl fragments at the ylide center. Russ J Gen Chem 79, 1467–1472 (2009). https://doi.org/10.1134/S107036320907010X

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  • DOI: https://doi.org/10.1134/S107036320907010X

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