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New method of synthesis 1-halogermatranes, germatranyl esters of H-O acids, and their stereoelectronic structure

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Abstract

A fundamentally new method for the synthesis of 1-halogermatranes and germatranyl esters of oxygen-containing acids has been developed. Using this method germatranes XGe(OCH2CH2)3N (X = Hal, ClO4)were synthesized, their elemental analysis was determined, and their stereoelectronic structure was studied by the methods of multinuclear NMR, mass spectrometry, and IR spectroscopy. The obtained data correlate with the results of quantum chemical calculations.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. G. Voronkov, T. A. Kochina, D. V. Vrazhnov & G. S. Samokhin

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034, Russia

    A. I. Albanov, T. N. Aksamentova, L. V. Klyba & N. N. Chipanina

Authors
  1. M. G. Voronkov
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  2. T. A. Kochina
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  3. D. V. Vrazhnov
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  4. G. S. Samokhin
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  5. A. I. Albanov
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  6. T. N. Aksamentova
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  7. L. V. Klyba
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  8. N. N. Chipanina
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Correspondence to M. G. Voronkov.

Additional information

Original Russian Text © M.G. Voronkov, T.A. Kochina, D.V. Vrazhnov, G.S. Samokhin, A.I. Albanov, T.N. Aksamentova, L.V. Klyba, N.N. Chipanina, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 12, pp. 1994–1998.

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Voronkov, M.G., Kochina, T.A., Vrazhnov, D.V. et al. New method of synthesis 1-halogermatranes, germatranyl esters of H-O acids, and their stereoelectronic structure. Russ J Gen Chem 78, 2339–2343 (2008). https://doi.org/10.1134/S1070363208120086

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  • DOI: https://doi.org/10.1134/S1070363208120086

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