Abstract
By thermogravimetry, the IR and electronic spectroscopy physicochemical characteristics of systems including aromatic aldehydes, 2,4-dinitrophenylhydrazine, and a surfactant were investigated. Selective solubilization effect of the cationic surfactant (cetylpyridinium chloride) micelles on the aci-form of hydrazone arising in the alkaline medium was found. The universal character of solubilization by the cationic surfactant micelles in the aromatic aldehyde—2,4-dinitrophenylhydrazine systems was shown by an example of the benzaldehyde derivatives with substituents of different nature. This effect leads to the increase in solubility of the reaction products and the aggregative stability of solutions.
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Original Russian Text © S.Yu. Doronin, R.K. Chernova, A.A. Burmistrova, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 5, pp. 761–765.
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Doronin, S.Y., Chernova, R.K. & Burmistrova, A.A. Effect of the micellar surfactant nanoreactors on the reactions of 2,4-dinitrophenylhydrazine with some aldehydes. Russ J Gen Chem 78, 903–907 (2008). https://doi.org/10.1134/S1070363208050113
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DOI: https://doi.org/10.1134/S1070363208050113