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Synthesis and crystal structure of π complex of copper(I) chloride with diallyl trisulfide 2CuCl · DATrS

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Abstract

Crystals of the π complex 2CuCl·DATrS (DATrS = diallyl trisulfide) were prepared by ac electrochemical synthesis and studied by X-ray diffraction. The crystals are monoclinic, space group C2, Z = 2, a = 12.737(1) Å, b = 5.0984(5) Å, c = 8.9263(7) Å, β = 101.159(5)°, V = 568.72(8) Å3. The structure contains infinite coils of (CuCl)n, which are united into a three-dimensional structure by the bibridge tetradentate ligand DATrS symmetric to axis 2. The trigonal-pyramidal surrounding of the Cu atom consists of two Cl atom, the olefine C=C group, and the S atom (in the apical position) of different DATrS molecules.

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Authors and Affiliations

  1. National University of Forestry and Wood Technology of Ukraine, Lviv, Ukraine

    N. F. Salivon

  2. Institute of Chemistry, University of Opole, Poland

    V. V. Olijnik

  3. Franko National University, ul. Kirilla i Mefodiya 6, Lviv, 79005, Ukraine

    A. A. Shkurenko

Authors
  1. N. F. Salivon
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  2. V. V. Olijnik
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  3. A. A. Shkurenko
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Original Russian Text © N.F. Salivon, V.V. Olijnik, A.A. Shkurenko, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 12, pp. 924–929.

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Salivon, N.F., Olijnik, V.V. & Shkurenko, A.A. Synthesis and crystal structure of π complex of copper(I) chloride with diallyl trisulfide 2CuCl · DATrS. Russ J Coord Chem 33, 908–913 (2007). https://doi.org/10.1134/S1070328407120068

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  • DOI: https://doi.org/10.1134/S1070328407120068

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