Skip to main content
SpringerLink
Log in

Synthesis and characterization of Ni(II) and Co(II) complexes of Schiff bases derived from 3,4-dimethyl-Δ3-tetrahydrobenzaldehyde and 4,6-dimethyl-Δ3-tetrahydrobenzaldehyde and glycene

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The Schiff bases derived from 3,4-dimethyl-Δ3-tetrahydrobenzaldehyde or 4,6-dimethyl-Δ3-tetrahydrobenzaldehyde and glycine and their complexes with nickel (II) and copper (II) were synthesized and investigated. All compounds were characterized by elemental analyses, conductivity measurements, and FT-IR spectroscopy. The Schiff base ligands and their complexes were further characterized by 1H NMR. The results suggest that the Schiff base acts as a bidentate ligand, which bonds to the metal ions through the imino nitrogen and carboxylate oxygen. The potassium salts of the Schiff bases are 1 : 1 electrolytes but all the complexes are nonelectrolytes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Güler, E., Sevindir, H.C., Kurbanov, S., and Mirzaoğlu, R., Synth. React. Inorg. Met.-Org. Chem., 1998, vol. 28, p. 295.

    Google Scholar 

  2. Zhang, W., Zishen, W., Zhenhuan, Y., et al., Synth. React. Inorg. Met.-Org. Chem., 1994, vol. 24, p. 1453.

    Article  Google Scholar 

  3. İbrahim, S.A., Shaker, A.M., İsmail, N.M., and Mahmoud, M.R., Synth. React. Inorg. Met.-Org. Chem, 1994, vol. 24, p. 1537.

    Article  Google Scholar 

  4. Chayanov, N., J. Gen. Chem., 1938, vol. 8, p. 460.

    CAS  Google Scholar 

  5. Nakamoto K., Infra-red and Raman Spectra of Inorganic and Coordination Compounds, New York: John Wiley and Sons, 1978, p. 10.

    Google Scholar 

  6. Sevindir, H.C., Mirzaoğlu, R., Özcan, E., et al., Synth. React. Inorg. and Met.-Org. Chem., 1994, vol. 24, p. 613.

    Article  CAS  Google Scholar 

  7. Karatas, İ. and Irez, G., Macromol. Rep., 1993, vol. 30A, no. 3–4, p. 241.

    Google Scholar 

  8. Mercimek, B. and Irez, G., Macromol. Rep., 1995, vol. 32A, no. 1–2, p. 147.

    Google Scholar 

  9. Özcan, E. and Mirzaoglu, R., Synth. React. Inorg. Met.-Org. Chem., 1983, vol. 13, p. 781.

    Article  Google Scholar 

  10. Ahsen, V., Gokceli, F., and Bekaroglu, Ö., Dalton Trans., 1987, p. 1827.

  11. Yılmaz, M., Synth. React. Inorg. Met.-Org. Chem., 1998, vol. 28, p. 1759.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Science and Arts, Department of Chemistry, Selcuk University, 42075, Kampüs Selçuklu, Konya, Turkey

    E. Güler & Ö. Koçyiğit

Authors
  1. E. Güler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ö. Koçyiğit
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Güler.

Additional information

The article was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Güler, E., Koçyiğit, Ö. Synthesis and characterization of Ni(II) and Co(II) complexes of Schiff bases derived from 3,4-dimethyl-Δ3-tetrahydrobenzaldehyde and 4,6-dimethyl-Δ3-tetrahydrobenzaldehyde and glycene. Russ J Coord Chem 33, 607–610 (2007). https://doi.org/10.1134/S1070328407080106

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328407080106

Keywords

Search

Navigation