Abstract
Separation of 241Am(III), 152+154Eu(III), and 60Co(II) radionuclides from nitric acid solutions by the batch method using KU-2, TRU, and Amberlite® IR-120(H) resins was studied. The separation factors (SFs) of radionuclides are affected by the HNO3 concentration and resin type. In 3 M HNO3, the SF of 152+154Eu from 60Co and 241Am with the KU-2 resin was 628 and 26.48, respectively. In 0.01 M HNO3, the SF of 241Am from 60Co with the TRU resin reached 83. All the resins used showed good radiation resistance and stability up to 100 kGy. Simulated nuclear liquid waste containing minor actinides (241Am), lanthanides (152+154Eu), fission products (137Cs and 99Mo), and activation products (60Co) was successfully treated using column chromatography with the KU-2 resin. The radionuclides were stripped using 1.5 M aqueous HNO3 with 70–82% degree of stripping in one stage. Thus, the KU-2 and TRU resins can be used for treatment of the high level corrosion products containing trivalent long-lived minor actinides (5d elements, e.g., Am and Cm), lanthanides (4f elements) and/or divalent heavy metals (3d elements), associated with a nuclear power plant.
Similar content being viewed by others
REFERENCES
Popova, N.N., Zhilov, V.I., Demin, S.V., and Tsivadze, A.Yu., Russ. J. Inorg. Chem., 2015, vol. 60, no. 6, pp. 754–758.
Madic, C., Hudson, M.J., Liljenzin, J.O., Glatz, J.P., Nannicini, R., Facchini, A., Kolarik, Z., and Odoj, R., New Partitioning Techniques for Minor Actinides, EUR 19149 EN, 2000.
Hideya, S., Yasuhiro, T., Tatsuya, K., Mitsunobu, S., Tomohiro, K., Shunichi, U., and Tatsuro, M., Anal. Sci., 2016, vol. 32, pp. 477–479.
Oigawa, H., Nishihara, K., Nakayama, S., and Morita, Y., Proc. 10th Information Exchange Meet., Mito (Japan): OECD/NEA, 2010.
Shu, Q., Khayambashi, A., Zou, Q., Wang, X., Wei, Y., He, L., and Tang, F., J. Radioanal. Nucl. Chem., 2017, vol. 313, no. 1, pp. 29–37.
Yamaji, K., Nuclear Back-End and Transmutation Technology for Waste Disposal: beyond the Fukushima Accident, Nakajima, K., Ed., Tokyo: Springer, 2015.
Malmbeck, R., Nourry, C., Ougier, M., Souček, P., Glatz, J., Kato, T., and Koyama, T., Energy Procedia, 2011, vol. 7, pp. 93–102.
Herbst, R.S., Law, J.D., Todd, T.A., Romanovskiy, V.N., Babain, V.A., Esimantovskiy, V.M., Smirnov, I.V., and Zaitsev, B.N., Solvent Extr. Ion Exch., 2002, vol. 20, pp. 429–445.
Ossola, A., Macerata, E., Tinonin, D.A., Faroldi, F., Giola, M., Mariani, M., and Casnati, A., Radiat. Phys. Chem., 2016, vol. 124, pp. 246–251.
Ruiqin, L, Yuezhou, W, Tozawa, D, Yuanlai, X, Usuda, S, Yamazaki, H, Ishii, K., Sano, Y., and Koma, Y., Nucl. Sci. Technol., 2011, vol. 22, pp. 18–24.
Attallah, M.F., Borai, E.H., and Allan, K.F., Radiochemistry, 2009, vol. 51, no. 6, pp. 622–627.
El-Khouly, S.H., Attallah, M.F., and Allan, K.F., Radiochemistry, 2013, vol. 55, no. 5, pp. 486–491.
El Afifi, E.M., Attallah, M.F., and Borai, E.H., J. Environ. Radioact., 2016, vol. 151, part 1, pp. 156–165.
Allan, K.F., El Afifi, E.M., and Holial, M., Particulate Sci. Technol., 2017, vol. 35, no. 2, pp. 127–138.
Khalil, M., El-Aryan, Y.F., and El Afifi, E.M., Particulate Sci. Technol., 2017, vol. 36, no. 5, pp. 618–627. https://doi.org/10.1080/02726351.2017.1287141
Naushad, Mu., Mitra, R., and Raghuvanshi, J., Ion Exchange Lett., 2009, vol. 2, pp. 31–34.
Carter, H., Uranium separation using extraction chromatography, PhD Thesis, Loughborough Univ. (the United States), 2000, pp. 22–26.
Borai, E.H., Hilal, M.A., Attallah, M.F., and Shehata, F.A., Radiochim. Acta, 2008, vol. 96, pp. 441–447.
Nilchi, A., Atashi, H., Javid, A.H., and Saberi, R., Appl. Radiat. Isot., 2007, vol. 65, pp. 482–487.
Someda, H.H., Ezz El-Din, M.R., Sheha, R.R., and El Naggar, H.A., J. Radioanal. Nucl. Chem., 2002, vol. 254, no. 2, pp. 373–378.
Sheha, R.R. and Someda, H.H., New Research on Hazardous Materials, Warey, P.B., Ed., New York: Nova Science, 2007, ch. 1, pp. 1–73.
Shannon, D., Acta Crystallogr., Sect. A, 1976, vol. 32, pp. 751–767.
Persson, I., Pure Appl. Chem., 2010, vol. 82, no. 10, pp. 1901–1917.
Saeed, M.M., J. Radioanal. Nucl. Chem., 2003, vol. 256, no. 1, pp. 73–80.
El-Said, H., J. Chem., 2012, Art. ID756876. https://doi.org/10.1155/2013/756876
Afsar, A., Distler, P., Harwood, L.M., John, J., and Westwood, J., Chem. Commun., 2017, vol. 53, pp. 4010–4013.
Popova, N.N., Zhilov, V.I., Demin, S.V., Tsivadze, A.Y., Yakshin, V.V., and Vilkova, O.M., Russ. J. Inorg. Chem., 2011, vol. 56, no. 7, pp. 1128–1132.
Saipriya, G., Kumaresan, R., Nayak, P.K., Venkatesan, K.A., Antony, M.P., and Kumar, T., J. Radioanal. Nucl. Chem., 2017, vol. 314, no. 3, pp. 2557–2568.
Larkin, P.J., in Infrared and Raman Spectroscopy: Principles and Spectral Interpretation, Amsterdam: Elsevier, 2012.
Segneanu, A.E., Gozescu, I., Dabici, A., Sfirloaga, P., and Szabadai, Z., Macro to Nano Spectroscopy, Uddin, J., Ed., InTech, 2012. http://www.intechopen.com/books/macro-to-nano-spectroscopy/organiccompounds-ft-ir-spectroscopy
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Attallah, M.F., Afifi, E.M.E. & Shehata, F.A. Performance of Some Ion-Exchange Resins in Removal of 241Am(III), 152+154Eu(III), 99Mo(VI), 137Cs(I), and 60Co(II) from Simulated Nuclear Acidic Solutions. Radiochemistry 62, 681–688 (2020). https://doi.org/10.1134/S1066362220050161
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1066362220050161