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Interaction of methanesulfonic acid with actinide ions. The new complexes HImid[Np(C2O4)(CH3SO3)3(H2O)2], [NpO2(Terpy)(CH3SO3)(H2O)]·2H2O, and [UO2(CH3SO3)2(H2O)]

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Abstract

Complexation of methanesulfonic acid with Np(IV), Np(V), and U(VI) ions in aqueous solutions was studied. New crystalline compounds HImid[Np(C2O4)(CH3SO3)3(H2O)2] (I), [NpO2(Terpy)(CH3SO3)·(H2O)]·2H2O (II), and [UO2(CH3SO3)2(H2O)] (III) were isolated. The absorption spectra of all the compounds in the IR, visible, and UV ranges were examined. The relationship between the composition, crystal structure, and IR and electronic absorption spectra of the complexes is discussed.

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References

  1. Panter, R. and Penzhorn, R.-D., Atmosph. Environ., 1980, vol. 14, pp. 149–151.

    Article  CAS  Google Scholar 

  2. Watts, S.F., Brimblecomble, P., and Watson, A.J., Atmosph. Environ., 1990, vol. 24A, pp. 353–359.

    CAS  Google Scholar 

  3. Saltzman, E.S., Savoic, D.L., Zika, R.G., and Prospero, J.M., J. Geophys. Res., 1983, vol. 88, pp. 10 897–10 907.

    Article  CAS  Google Scholar 

  4. Mukai, H., Yokouchi, Y., and Sozuki, M., Atmosph. Environ., 1995, vol. 29, no. 14, pp. 1637–1648.

    Article  CAS  Google Scholar 

  5. Hotakeyama, S., Okudo, M., and Akimoto, H., Geophys. Res. Lett., 1982, vol. 9, pp. 583–586.

    Article  Google Scholar 

  6. Kelly, D.P. and Murrel, J.C., Arch. Microbiol., 1999, vol. 172, pp. 341–348.

    Article  CAS  Google Scholar 

  7. Cook, A.M., Laue, H., and Junker, F., Microb. Rev., 1999, vol. 22, pp. 399–419.

    Google Scholar 

  8. Zhao, P., Allen, P.G., Sylvestr, E.R., and Vani, B.E., Radiochim. Acta, 2000, vol. 88, p. 729.

    Article  CAS  Google Scholar 

  9. Wei, C.H. and Hingerty, B.E., Acta Crystallogr., Sect. B, 1981, vol. 37, no. 11, pp. 1992–1997.

    Article  Google Scholar 

  10. Wei, C.H., Acta Crystallogr., Sect. C, 1986, vol. 42, no. 10, pp. 1839–1842.

    Article  Google Scholar 

  11. Arico, E.H., Zinner, L.B., Apostilidis, C., et al., J. Alloys Comp., 1997, vol. 249, nos. 1–2, pp. 110–114.

    Google Scholar 

  12. Wilson, A.S., Acta Crystallogr., Sect. B, 1978, vol. 34, p. 2302.

    Article  Google Scholar 

  13. Frisch, M. and Cahill, C., J. Solid State Chem., 2007, vol. 180, p. 2597.

    Article  CAS  Google Scholar 

  14. Bradley, A.E., Hatter, J.E., Nieuwenhuyzen, M., et al., Inorg. Chem., 2002, vol. 41, p. 1692.

    Article  CAS  Google Scholar 

  15. Andreev, G.B., Budantseva, N.A., Tananaev, I.G., and Myasoedov, B.F., Inorg. Chem. Commun., 2008, vol. 11, p. 802.

    Article  CAS  Google Scholar 

  16. Andreev, G.B., Budantseva, N.A., Tananaev, I.G., and Myasoedov, B.F., Acta Crystallogr., Sect. E, 2007, vol. 63, p. m3159.

    Article  Google Scholar 

  17. The Chemistry of the Actinide Elements, Katz, J.J., Seaborg, G.T., and Morss, L.R., Eds., London: Chapman and Hall, 1986, 2nd ed. Translated under the title Khimiya aktinidov, Moscow: Mir, 1991, vol. 1, p. 503.

    Google Scholar 

  18. Ryan, J.L., Inorg. Chem., 1972, vol. 7, p. 323.

    CAS  Google Scholar 

  19. Charushnikova, I.A., Krot, N.N., and Katser, S.B., Radiokhimiya, 1998, vol. 40, no. 6, p. 538.

    Google Scholar 

  20. Charushnikova, I.A., Garnov, A.Yu., Perminov, V.P., et al., Radiokhimiya, 1998, vol. 40, no. 4, p. 302.

    Google Scholar 

  21. Garnov, A.Yu., Krot, N.N., and Perminov, V.P., Radiokhimiya, 1998, vol. 40, no. 1, p. 9.

    Google Scholar 

  22. Budantseva, N.A., Andreev, G.B., Fedoseev, A.M., and Antipin, M.Yu., Radiokhimiya, 2003, vol. 45, no. 4, p. 303.

    Google Scholar 

  23. Reich, T., Bernhard, G., Geipel, G., et al., Radiochim. Acta, 2000, vol. 88, p. 633.

    Article  CAS  Google Scholar 

  24. Allen, P.G., Bacher, J.J., Shuh, D.K., et al., Inorg. Chem., 1997, vol. 36, p. 4676.

    Article  CAS  Google Scholar 

  25. Excoffon, P. and Marechal, Y., Chem. Phys., 1980, vol. 52, p. 237.

    Article  CAS  Google Scholar 

  26. Lantie, A. and Bellabes, Y., Spectrochim. Acta, 1996, vol. 52, p. 1903.

    Article  Google Scholar 

  27. Scott, K.L., Wieghardt, K., and Sykes, A.G., Inorg. Chem., 1973, vol. 12, p. 655.

    Article  CAS  Google Scholar 

  28. Simon, A. and Kriegsmann, H., Chem. Ber., 1956, vol. 89, p. 2384.

    Article  CAS  Google Scholar 

  29. Ienco, A., Mealli, C., Paoli, P., et al., New J. Chem., 1999, vol. 23, p. 1253.

    Article  CAS  Google Scholar 

  30. Matsika, S., Pitzer, R., and Reed, D., J. Chem. Phys. (A), 2000, vol. 104, p. 11 983.

    CAS  Google Scholar 

  31. Budantseva, N., Andreev, G., and Fedosseev, A., C. R. Acad. Sci. Paris, 2005, vol. 8, p. 91.

    CAS  Google Scholar 

  32. Kopashova, I.M., Skutov, I.K., Umreiko, D.S., et al., Zh. Neorg. Khim., 1967, vol. 12, no. 12, p. 3304.

    CAS  Google Scholar 

  33. Wong, P.T. and Brever, D.J., Can. J. Chem., 1960, vol. 47, no. 24, p. 4589.

    Article  Google Scholar 

  34. Vdovenko, V.M., Skoblo, A.I., and Suglobov, D.N., Radiokhimiya, 1969, vol. 11, no. 1, p. 30.

    CAS  Google Scholar 

  35. Vdovenko, V.M., Skoblo, A.I., Suglobov, D.N., et al., Radiokhimiya, 1968, vol. 10, no. 5, p. 527.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    G. B. Andreev, N. A. Budantseva, I. G. Tananaev & B. F. Myasoedov

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  1. G. B. Andreev
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  2. N. A. Budantseva
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  3. I. G. Tananaev
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  4. B. F. Myasoedov
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Original Russian Text © G.B. Andreev, N.A. Budantseva, I.G. Tananaev, B.F. Myasoedov, 2009, published in Radiokhimiya, 2009, vol. 51, no. 3, pp. 197–201.

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Andreev, G.B., Budantseva, N.A., Tananaev, I.G. et al. Interaction of methanesulfonic acid with actinide ions. The new complexes HImid[Np(C2O4)(CH3SO3)3(H2O)2], [NpO2(Terpy)(CH3SO3)(H2O)]·2H2O, and [UO2(CH3SO3)2(H2O)]. Radiochemistry 51, 225–230 (2009). https://doi.org/10.1134/S1066362209030023

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  • DOI: https://doi.org/10.1134/S1066362209030023

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