Abstract
Compounds M I2 Th(NO3)6 (MK = NH4, K, Rb, Cs) were precipitated from a solution. The structure and thermolysis of these compounds were studied by X-ray diffraction, precision IR spectroscopy, and thermal analysis. Their previously unknown standard enthalpies of formation at 298.15 K were determined by reaction calorimetry.
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References
The Chemistry of the Actinide Elements, Katz, J., Seaborg, G., and Morss, L., Eds., New York: Chapman and Hall, 1986, vol. 1.
Spirlet, M.R., Rebizant, J., Apostolidis, C., et al., Acta Crystallogr., Sect. C., 1992, vol. 48, pp. 1161–1164.
Chernorukov, N.G., Mikhailov, Yu.N., Knyazev, A.V., et al., Koord. Khim., 2007, vol. 33, no. 2, pp. 151–154.
Karyakin, N.V., Chernorukov, N.G., Knyazev A.V., et al., Zh. Fiz. Khim., 2002, vol. 76, no. 3, pp. 420–423.
Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko V.P., Ed., Moscow: Akad. Nauk SSSR, 1968–1981, issues I–X.
CODATA Key Values, J. Chem. Thermodyn., 1971, vol. 3, no. 1, pp. 4–17.
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Original Russian Text © A.V. Knyazev, A.A. Sazonov, N.Yu. Kuznetsova, 2008, published in Radiokhimiya, 2008, Vol. 50, No. 4, pp. 301–302.