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Physical chemistry of magnesium and calcium uranophosphate and uranoarsenate AII(BVUO6)2·nH2O

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Abstract

Temperature dependences of the isobaric heat capacity of AII(BVUO6)2·nH2O (AII = Mg, Ca; BV = P, As) was measured. The standard entropies and Gibbs energies of formation of the compounds were calculated. From these values, the solubility of the compounds in water at T = 25°C was evaluated.

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References

  1. Sidorenko, G.A., Kristallokhimiya mineralov urana (Crystal Chemistry of Uranium-Containing Minerals), Moscow: Atomizdat, 1978.

    Google Scholar 

  2. Miller, S.A. and Taylor, J.C., Z. Kristallogr., 1986, vol. 177, pp. 247–253.

    CAS  Google Scholar 

  3. Makarov, E.S. and Ivanov, V.I., Dokl. Akad. Nauk SSSR, 1960, vol. 132, no. 3, pp. 673–676.

    CAS  Google Scholar 

  4. Chernorukov, N.G., Karyakin, N.V., Suleimanov, E.V., and Belova, Yu.S., Zh. Neorg. Khim., 1996, vol. 41, no. 1, pp. 39–42.

    CAS  Google Scholar 

  5. Chernorukov, N.G., Karyakin, N.V., Suleimanov, E.V., and Belova, Yu.S., Zh. Neorg. Khim., 1998, vol. 43, no. 3, pp. 380–383.

    CAS  Google Scholar 

  6. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., et al., Zh. Neorg. Khim., 1998, vol. 43, no. 10, pp. 1672–1676.

    CAS  Google Scholar 

  7. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., et al., Zh. Fiz. Khim., 2000, vol. 74, no. 4, pp. 581–585.

    CAS  Google Scholar 

  8. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., and Mochalov, L.A., Zh. Obshch. Khim., 1998, vol. 68, no. 3, pp. 372–374.

    Google Scholar 

  9. Parks, G.S. and Huffman, H.M., The Free Energies of Some Organic Compounds, New York: Chem. Catalog, 1932.

    Google Scholar 

  10. Termicheskie konstanty veschestv (Thermal Constants of Substances), Glushko, V.P., Ed., Moscow: Nauka, 1965–1981, issues I–X.

    Google Scholar 

  11. Shvarov, Yu.V., Geokhimiya, 1999, vol. 37, no. 6, pp. 646–652.

    Google Scholar 

  12. Naumov, G.B., Ryzhenko, B.N., and Khodakovskii, I.L., Spravochnik termodinamicheskikh velichin (Handbook of Thermodynamic Quantities), Moscow: Atomizdat, 1971.

    Google Scholar 

  13. Rutsch, M., Geipel, G., Brendler, V., et al., Radiochim. Acta, 1999, vol. 86, pp. 135–141.

    CAS  Google Scholar 

  14. Zhil’tsova, I.G., Shmariovich, E.M., Polupanova, L.I., and Perlina, S.A., Litol. Polezn. Iskop., 1982, no. 6, pp. 49–60.

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Original Russian Text © E.V. Suleimanov, N.G. Chernorukov, V.V. Veridusova, 2006, published in Radiokhimiya, 2006, Vol. 48, No. 2, pp. 144–145.

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Suleimanov, E.V., Chernorukov, N.G. & Veridusova, V.V. Physical chemistry of magnesium and calcium uranophosphate and uranoarsenate AII(BVUO6)2·nH2O. Radiochemistry 48, 159–161 (2006). https://doi.org/10.1134/S106636220602010X

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  • DOI: https://doi.org/10.1134/S106636220602010X

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