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Synthesis and Properties of Calcium, Strontium, and Barium Uranates

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Abstract

Pure crystalline compounds MIIU3O10 · n H2O (MII = Ca, Sr) and BaU2O7 · 3 H2O were obtained by reactions of synthetic schoepite (UO3 · 2.25 H2O) with aqueous solutions of calcium, strontium, and barium nitrates under hydrothermal conditions at 200°C and pH 7‒8. Their structure, dehydration, and thermal decomposition were studied by chemical analysis, X-ray fluorescence spectrometry, X-ray powder diffraction, IR spectroscopy, and thermogravimetric analysis.

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References

  1. Chernorukov, N.G., Nipruk, O.V., Knyazev, A.V., Arova, M.I., and Chaplieva, K.A., Russ. J. Inorg. Chem., 2013, vol. 58, no. 1, p. 9. doi https://doi.org/10.1134/S0036023613010051

    Article  CAS  Google Scholar 

  2. Chernorukov, N.G., Nipruk, O.V., Chernorukov, G.N., and Sedelkina, O.S., Radiochemistry, 2015, vol. 57, no. 4, p. 378. doi https://doi.org/10.1134/S1066362215040062

    Article  CAS  Google Scholar 

  3. Finch, R.J., Burns, P.C., Hawthorne, F.C., and Ewing, R.C., Can. Mineral., 2006, vol. 44, p. 1197.

    Article  CAS  Google Scholar 

  4. Cejka, J., Sejkora, J., Skala, R., Cejka, J., Novotna, M., and Ederova, J., Neues Jahrb. Mineral., Abh., 1998, vol. 174, p. 159.

    CAS  Google Scholar 

  5. Pagoaga, M.K., Appleman, D.E., and Stewart, J.M., Mineral. Mag., 1986, vol. 50, p. 125.

    Article  Google Scholar 

  6. Pagoaga, M.K., Appleman, D.E., and Stewart, J.M., Am. Mineral., 1987, vol. 72, p. 1230.

    CAS  Google Scholar 

  7. Sobry, R., J. Inorg. Nucl. Chem., 1973, vol. 35, no. 5, p. 1516. doi https://doi.org/10.1016/0022-1902(73)80240-4

    Article  Google Scholar 

  8. Sobry, R., J. Inorg. Nucl. Chem., 1973, vol. 35, no. 8, p. 2754. doi https://doi.org/10.1016/0022-1902(73)80506-8

    Article  Google Scholar 

  9. Dunn, H., X-Ray Diffraction Data for Some Uranium Compounds, ORNL-2092, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 1956.

    Google Scholar 

  10. Peters, J., Mem. Soc. Roy. Sci. Liege, 1967, p. 5.

    Google Scholar 

  11. Volod’ko, M.V., Komyak, A.I., and Umreiko, D.S., Uranilovye soedineniya (Uranyl Compounds). Minsk: Belarus. Gos. Univ., 1981, vol. 1.

  12. Yukhnevich, G.V., Infrakrasnaya spektroskopiya vody (Infrared Spectroscopy of Water), Moscow: Nauka, 1973.

    Google Scholar 

  13. Cordfunke, E.H.P. and Loopstra, B.O., J. Inorg. Nucl. Chem., 1967, vol. 29, p. 51. doi https://doi.org/10.1016/0022-1902(67)80143-X

    Article  CAS  Google Scholar 

  14. Sali, S.K., Sampath, S., and Venugopal, V., J. Nucl. Mater., 2000, vol. 277, p. 106. doi https://doi.org/10.1016/S0022-3115(99)00145-2

    Article  CAS  Google Scholar 

  15. Allen, G.C. and Griffiths, A.J., J. Chem. Soc., Dalton Trans., 1979, p. 315. doi https://doi.org/10.1039/dt9790000315

    Google Scholar 

  16. Loopstra, B.O. and Rietveld, H.M., Acta Crystallogr., Sect. B, 1969, vol. 25, p. 787. doi https://doi.org/10.1107/S0567740869002974

    Article  CAS  Google Scholar 

  17. Nipruk, O.V., Knyazev, A.V., Chernorukov, G.N., and Pykhova, Yu.P., Radiochemistry, 2011, vol. 53, no. 2, p. 146. doi https://doi.org/10.1134/S1066362211020044

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Lobachevskii Nizhny Novgorod State University, pr. Gagarina 23a, Nizhny Novgorod, 603950, Russia

    N. G. Chernorukov, O. V. Nipruk, G. N. Chernorukov, R. V. Abrazheev & K. A. Chaplieva

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  1. N. G. Chernorukov
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  2. O. V. Nipruk
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  3. G. N. Chernorukov
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  4. R. V. Abrazheev
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  5. K. A. Chaplieva
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Corresponding author

Correspondence to O. V. Nipruk.

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Russian Text © N.G. Chernorukov, O.V. Nipruk, G.N. Chernorukov, R.V. Abrazheev, K.A. Chaplieva, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 1, pp. 83–88.

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Chernorukov, N.G., Nipruk, O.V., Chernorukov, G.N. et al. Synthesis and Properties of Calcium, Strontium, and Barium Uranates. Russ J Gen Chem 89, 71–75 (2019). https://doi.org/10.1134/S1070363219010134

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  • DOI: https://doi.org/10.1134/S1070363219010134

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