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Distribution of Mn2+ Manganese Ions in a Single Crystal of the Lithium–Gallium Li0.5Ga2.5O4 Spinel

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Abstract

A self-organization of eight structurally and magnetically nonequivalent positions of manganese Mn2+ ions in the unit cell of a single crystal of the lithium–gallium Li0.5Ga2.5O4 spinel is demonstrated. These ions are self-distributed over such positions and minima of the crystal field potential. The self-organized structures form during the crystal growth. Such a self-distribution of manganese ions is observed and studied in the electron paramagnetic resonance (EPR) spectra.

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ACKNOWLEDGMENTS

The authors are very grateful to the Leadership and Teaching Staff of the Organization “Mathematics for America” (Math for America), in particular to Prof. John Ewing as an inspirer, Ms. Courtney Allison and Mr. Michael Driskill for support.

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Authors and Affiliations

  1. Math for America (MfA), New, York, USA

    V. V. Shapovalov

  2. Galkin Donetsk Institute for Physics and Technology, Donetsk, Ukraine

    V. A. Shapovalov & V. I. Val’kov

  3. Kotel’nikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences, Moscow, Russia

    V. G. Shavrov, V. V. Koledov & A. P. Kamantsev

Authors
  1. V. V. Shapovalov
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  2. V. A. Shapovalov
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  3. V. G. Shavrov
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  4. V. V. Koledov
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  5. V. I. Val’kov
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  6. A. P. Kamantsev
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Correspondence to V. A. Shapovalov.

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The authors declare that they have no conflicts of interest.

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Translated by Yu. Ryzhkov

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Shapovalov, V.V., Shapovalov, V.A., Shavrov, V.G. et al. Distribution of Mn2+ Manganese Ions in a Single Crystal of the Lithium–Gallium Li0.5Ga2.5O4 Spinel. Phys. Solid State 63, 650–653 (2021). https://doi.org/10.1134/S1063783421040211

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  • DOI: https://doi.org/10.1134/S1063783421040211

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