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Peculiarities of EPR in polycrystalline solid solutions Zn0.95Fe0.05O with different particles morphology: The role of intrinsic defects in formation of magnetic properties

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Abstract

Single-phase polycrystalline samples of Zn0.95Fe0.05O having the wurtzite structure and different morphology of particles were obtained using precursor technologies. It was found by electron spin resonance that iron enters the ZnO crystal lattice in the Fe3+ charge state. Magnetic studies revealed that the obtained samples show weak ferromagnetic properties at 300 K. A correlation between the number of oxygen vacancies and the degree of ferromagnetic ordering was found.

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References

  1. Tables of Physical Values, The Handbook, Ed. by I. K. Kikoin (Atomizdat, Moscow, 1976) [in Russian].

  2. X. X. Wei, C. Song, K. W. Geng, F. Zeng, B. He, and F. Pan, J. Phys.: Condens. Matter 18, 7471 (2006).

    ADS  Google Scholar 

  3. M. S. Park and B. I. Min, Phys. Rev. B 68, 224436 (2003).

    Article  ADS  Google Scholar 

  4. B. Pandey, S. Ghosh, P. Srivastava, D. K. Avasthi, D. Kabiraj, and J. C. Pivin, J. Magn. Magn. Mater. 320, 3347 (2008).

    Article  ADS  Google Scholar 

  5. P. K. Sharma, R. K. Dutta, and A. C. Pandey, J. Magn. Magn. Mater. 321, 4001 (2009).

    Article  ADS  Google Scholar 

  6. R. P. Borges, J. V. Pinto, R. C. da Silva, A. P. Gonçalves, M. M. Cruz, and M. Godinho, J. Magn. Magn. Mater. 316, e191 (2007).

    Article  Google Scholar 

  7. S. Ghoshal and P. S. Anil Kumar, J. Magn. Magn. Mater. 320, L93 (2008).

    Article  ADS  Google Scholar 

  8. S. J. Pearton, C. R. Abernathy, M. E. Overberg, G.T. Thaler, D. P. Norton, N. Theodoropoulou, A. F. Hebard, Y. D. Park, F. Ren, J. Kim, and L. A. Boatner, J. Appl. Phys. 93, 1 (2003).

    Article  ADS  Google Scholar 

  9. W. Prellier, A. Fouchet, and B. Mercey, J. Phys.: Condens. Matter. 15, R1583 (2003).

    ADS  Google Scholar 

  10. R. Janisch, P. Gopal, and N. A. Spaldin, J. Phys.: Condens. Matter. 17, R657 (2005).

    ADS  Google Scholar 

  11. S. J. Pearton, W. H. Heo, M. Ivill, D. P. Norton, and T. Steiner, Semicond. Sci. Technol. 19, R59 (2004).

    Article  ADS  Google Scholar 

  12. F. Pan, C. Song, X. J. Liu, Y. C. Yang, and F. Zeng, Mater. Sci. Eng. R 62, 1 (2008).

    Article  Google Scholar 

  13. T. Dietl, H. Ohno, F. Matsukura, J. Cibert, and D. Ferrand, Science 287, 1019 (2000).

    Article  ADS  Google Scholar 

  14. S. Mal, J. Narayan, S. Nori, J. T. Prater, and D. Kumar, Solid State Commun. 150, 1660 (2010).

    Article  ADS  Google Scholar 

  15. R. Escudero and R. Escamilla, Solid State Commun. 151, 97 (2011).

    Article  ADS  Google Scholar 

  16. V. N. Krasil’nikov, T. V. Dyachkova, A. P. Tyutyunnik, V. V. Marchenkov, O. I. Gyrdasova, I. V. Baklanova, M. V. Kuznetsov, and H. W. Weber, Phys. Solid State 57, 1079 (2015).

    Article  ADS  Google Scholar 

  17. V. N. Krasilnikov, T. V. Dyachkova, O. I. Gyrdasova, A. P. Tyutyunnik, V. V. Marchenkov, and H. W. Weber, Mater. Chem. Phys. 162, 1 (2015).

    Article  Google Scholar 

  18. G. Y. Ahn, S. I. Park, and C. S. Kim, J. Magn. Magn. Mater. 303, e329 (2006).

    Article  Google Scholar 

  19. A. Samariya, R. K. Sighal, S. Kumar, Y. T. Xing, M. Alzamora, S. N. Dolia, U. P. Deshpande, T. Shripathi, and E. B. Saitovitch, Mater. Chem. Phys. 123, 678 (2010).

    Article  Google Scholar 

  20. X. Yu, D. Meng, C. Liu, K. Xu, J. Chen, and Y. Wang, Solid State Sci. 13, 388 (2011).

    Article  ADS  Google Scholar 

  21. O. I. Gyrdasova, V. N. Krasil’nikov, E. V. Shalaeva, L. Yu. Buldakova, M. Yu. Yanchenko, and V. G. Bamburov, Dokl. Chem. 434, 211 (2010).

    Article  Google Scholar 

  22. V. N. Krasil’nikov, O. I. Gyrdasova, L. Yu. Buldakova, and M. Yu. Yanchenko, Russ. J. Inorg. Chem. 56, 145 (2011).

    Article  Google Scholar 

  23. S. A. Altshuler and B. M. Kozyrev, Electron Paramagnetic Resonance in Compounds of Transition Elements (Wiley, New York, 1974, Nauka, Moscow, 1972).

    Google Scholar 

  24. M. A. Melkozerova, V. N. Krasil’nikov, O. I. Gyrdasova, E. V. Zabolotskaya, E. V. Shalaeva, and R. F. Samigullina, Theor. Exp. Chem. 48, 149 (2012).

    Article  Google Scholar 

  25. A. Janotti and C. G. van de Walle, Phys. Rev. B 76, 165202 (2007).

    Article  ADS  Google Scholar 

  26. L. S. Vlasenko, Appl. Magn. Reson. 39, 103 (2010).

    Article  Google Scholar 

  27. Yu. V. Yablokov, V. K. Voronkova, and L. V. Mosina, Paramagnetic Resonance of Exchange Clusters (Nauka, Moscow, 1988) [in Russian].

    Google Scholar 

  28. B. S. Tsukerblat and M. P. Chobanu, Sov. Phys. Solid State 18, 1232 (1976).

    Google Scholar 

  29. Yu. V. Yablokov, V. A. Gaponenko, A. V. Ablov, and T. N. Zhikharev, Sov. Phys. Solid State 15, 251 (1973).

    Article  Google Scholar 

  30. Ya. G. Klyava, EPR-Spectroscopy of Disordered Solids (Zinatne, Riga, 1988) [in Russian].

    Google Scholar 

  31. M. A. Melkozerova, V. N. Krasil’nikov, O. I. Gyrdasova, E. V. Shalaeva, I. V. Baklanova, L. Yu. Buldakova, and M. Yu. Yanchenko, Phys. Solid State 55, 2459 (2013).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    M. A. Melkozerova, O. I. Gyrdasova, T. V. D’yachkova, A. P. Tyutyunnik, V. V. Bannikov, E. V. Zabolotskaya & V. N. Krasil’nikov

  2. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    V. V. Marchenkov & Yu. A. Perevozchikova

  3. Ural Federal University named after the first President of Russia B.N. Yeltsin, Yekaterinburg, 620002, Russia

    V. V. Marchenkov

  4. TU Wien Atominstitut, Vienna, 1020, Austria

    F. Sauerzopf

Authors
  1. M. A. Melkozerova
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  2. O. I. Gyrdasova
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  3. T. V. D’yachkova
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  4. A. P. Tyutyunnik
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  5. V. V. Bannikov
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  6. E. V. Zabolotskaya
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  7. V. V. Marchenkov
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  8. Yu. A. Perevozchikova
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  9. F. Sauerzopf
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  10. V. N. Krasil’nikov
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Corresponding author

Correspondence to M. A. Melkozerova.

Additional information

Original Russian Text © M.A. Melkozerova, O.I. Gyrdasova, T.V. D’yachkova, A.P. Tyutyunnik, V.V. Bannikov, E.V. Zabolotskaya, V.V. Marchenkov, Yu.A. Perevozchikova, F. Sauerzopf, V.N. Krasil’nikov, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 8, pp. 1484–1489.

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Melkozerova, M.A., Gyrdasova, O.I., D’yachkova, T.V. et al. Peculiarities of EPR in polycrystalline solid solutions Zn0.95Fe0.05O with different particles morphology: The role of intrinsic defects in formation of magnetic properties. Phys. Solid State 59, 1506–1511 (2017). https://doi.org/10.1134/S1063783417080157

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  • DOI: https://doi.org/10.1134/S1063783417080157

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