Abstract
Most of the energy produced is lost, mainly as waste heat. Thermoelectricity, which can directly convert heat into electricity, is seen with huge potential to recover part of such heat. However, to be widely used, it is necessary to be based on cheap, available, non-toxic, stable and easy-to-produce good thermoelectric materials. Here we present an overview of the potential of Cu–S based synthetic minerals for thermoelectric applications. In particular, we focus on tetrahedrites, which are world spread minerals with Cu10M2Sb4Si3 (M = Cu, Mn, Fe, Co, Ni, Zn) general formula that show high potential for thermoelectrics. An overview of their properties are presented, with emphasis on those relevant for thermoelectric applications.
Similar content being viewed by others
REFERENCES
Energy and Environment Report, No 6/2008 (European Environment Agency, 2008). https://www.eea.europa.eu/publications/eea_report_2008_6
Fact Sheet 087-02, U.S. Geological Survey. http://pubs.usgs.gov/fs/2002/fs087-02/
A. P. Gonçalves, E. B. Lopes, J. Monnier, E. Alleno, C. Godart, M. F. Montemor, J.-B. Vaney, and B. Lenoir, Solid State Phenom. 257, 135 (2017).
L.-D. Zhao, S.-H. Lo, Y. Zhang, H. Sun, G. Tan, C. Uher, C. Wolverton, V. P. Dravid, and M. G. Kana-tzidis, Nature (London, U.K.) 508, 373 (2014).
M. K. Jana and K. Biswas, ACS Energy Lett. 3, 1315 (2018).
Y.-H. Ji, Z.-H. Ge, Z. Li, and J. Feng, J. Alloys Compd. 680, 273 (2016).
A. A. Olvera, N. A. Moroz, P. Sahoo, P. Ren, T. P. Bailey, A. A. Page, C. Uher, and P. F. P. Poudeu, Energy Environ. Sci. 10, 1668 (2017).
G. Agricolae, De natura fossilium (Textbook of Mineralogy) (Dover, Mineola, New York, 2004).
W. Haidinger, Handbuch der Bestimmenden Mineralogie (Braumüller and Seidel, Wien, 1845).
Tetrahedrite, Hudson Institute of Mineralogy. https://www.mindat.org/min-3924.html. Accessed April 22, 2019.
K. Suekuni, K. Tsuruta, T. Ariga, and M. Koyano, Appl. Phys. Express 5, 051201 (2012).
X. Lu, D. T. Morelli, Y. Xia, F. Zhou, V. Ozolins, H. Chi, X. Zhou, and C. Uher, Adv. Energy Mater. 3, 342 (2013).
K. Suekuni, K. Tsuruta, M. Kunii, H. Nishiate, E. Nishibori, S. Maki, M. Ohta, A. Yamamoto, and M. Koyano, J. Appl. Phys. 113, 043712 (2013).
Y. Bouyrie, C. Candolfi, A. Dauscher, B. Malaman, and B. Lenoir, Chem. Mater. 27, 8354 (2015).
Xu Lu and D. T. Morelli, in Materials Aspect of Thermoelectricity, Ed. by C. Uher (CRC, Taylor and Francis Group, Boca Raton, 2016).
B. J. Skinner, F. D. Luce, and E. Makovicky, Econ. Geol. 67, 924 (1972).
K. Tatsuka and N. Morimoto, Am. Mineral. 62, 1101 (1977).
M. H. Braga, J. A. Ferreira, C. Lopes, and L. F. Malheiros, Mater. Sci. Forum 587–588, 435 (2008).
T. Barbier, P. Lemoine, S. Gascoin, O. I. Lebedev, A. Kaltzoglou, P. Vaqueiro, A. V. Powell, R. I. Smith, and E. Guilmeau, J. Alloys Compd. 634, 253 (2015).
P. Lemoine, C. Bourgès, T. Barbier, V. Nassif, S. Cordier, and E. Guilmeau, J. Solid State Chem. 247, 83 (2017).
C. An, Y. Jin, K. Tang, and Y. Qian, J. Mater. Chem. 13, 301 (2003).
D. J. James, X. Lu, D. T. Morelli, and S. L. Brock, ACS Appl. Mater. Interfaces 7, 23623 (2015).
S. Fasolin, S. Fiameni, C. Fanciulli, S. Battiston, A. Famengo, and M. Fabrizio, J. Nanosci. Nanotechnol. 17, 1645 (2017).
M. D. Regulacio, S. Y. Tee, S. H. Lim, C. P. Teng, L.-D. Koh, S. Liu, and M.-Y. Han, Nanoscale 9, 17865 (2017).
D. P. Weller, D. L. Stevens, G. E. Kunkel, A. M. Ochs, C. F. Holder, D. T. Morelli, and M. E. Anderson, Chem. Mater. 29, 1656 (2017).
X. Lu and D. T. Morelli, MRS Commun. 3, 129 (2013).
T. Barbier, S. Rollin-Martinet, P. Lemoine, F. Gascoin, A. Kaltzoglou, P. Vaqueiro, A. V. Powell, and E. Guilmeau, J. Am. Ceram. Soc. 99, 51 (2016).
D. P. Weller and D. T. Morelli, J. Alloys Compd. 710, 794 (2017).
S. Battiston, C. Fanciulli, S. Fiameni, A. Famengo, S. Fasolin, and M. Fabrizio, J. Alloys Compd. 702, 75 (2017).
F.-H. Sun, C.-F. Wu, Z. Li, Y. Pan, Asfandiyar, J. Dong, and J.-F. Li, RSC Adv. 7, 18909 (2017).
S.-Y. Kim, S.-G. Kwak, J.-H. Pi, G.-E. Lee, and I.-H. Kim, J. Electron. Mater. 48, 1857 (2019).
F.-H. Sun, J. Dong, H. Tang, P.-P. Shang, H.-L. Zhuang, H. Hu, C.-F. Wu, Y. Pan, and J.-F. Li, Nano Energy 57, 835 (2019).
A. P. Gonçalves, E. B. Lopes, J. Monnier, J. Bourgon, J. B. Vaney, A. Piarristeguy, A. Pradel, B. Lenoir, G. Delaizir, M. F. C. Pereira, E. Alleno, and C. Godart, J. Alloys Compd. 664, 209 (2016).
A. U. Khan, N. Vlachos, and Th. Kyratsi, Scr. Mater. 69, 606 (2013).
J. Wang, M. Gu, Y. Bao, X. Li, and L. Chen, J. Electron Mater. 45, 2274 (2015).
A. P. Gonçalves, E. B. Lopes, B. Villeroy, J. Monnier, C. Godart, and B. Lenoir, RSC Adv. 6, 102359 (2016).
T. K. C. Alves, G. Domingues, E. B. Lopes, and A. P. Gonçalves, J. Electron. Mater. 48, 2028 (2019).
R. Chetty, A. Bali, M. H. Naik, G. Rogl, P. Rogl, M. Jain, S. Suwas, and R. C. Mallik, Acta Mater. 100, 266 (2015).
P. Qiu, M. T. Agne, Y. Liu, Y. Zhu, H. Chen, T. Mao, J. Yang, W. Zhang, S. M. Haile, W. G. Zeier, J. Janek, C. Uher, X. Shi, L. Chen, and G. J. Snyder, Nat. Commun. 9, 2910 (2018).
G. Dennler, R. Chmielowski, S. Jacob, F. Capet, P. Roussel, S. Zastrow, K. Nielsch, I. Opahle, and G. K. H. Madsen, Adv. Energy Mater. 4, 1301581 (2014).
E. Makovicky and B. J. Skinner, Can. Mineral. 17, 619 (1979).
N. Mozgova, V. Mikucionis, V. I. Valiukenas, A. Tsepin, and A. Orliukas, Phys. Chem. Miner. 15, 171 (1987).
P. Qiu, T. Zhang, Y. Qiu, X. Shi, and L. Chen, Energy Environ. Sci. 7, 4000 (2014).
P. Vaqueiro, G. Guélou, A. Kaltzoglou, R. I. Smith, T. Barbier, E. Guilmeau, and A. V. Powell, Chem. Mater. 29, 4080 (2017).
J. A. Ferreira and M. H. Braga, Mater. Sci. Forum 730–732, 111 (2013).
X. Fan, E. D. Case, X. Lu, and D. T. Morelli, J. Mater. Sci. 48, 7540 (2013).
R. Chetty, D. S. Prem Kumar, G. Rogl, P. Rogl, E. Bauer, H. Michor, S. Suwas, S. Puchegger, G. Giester, and R. C. Mallik, Phys. Chem. Chem. Phys. 17, 1716 (2015).
R. Chetty, A. Bali, M. H. Naik, G. Rogl, P. Rogl, M. Jain, S. Suwas, and R. C. Mallik, Acta Mater. 100, 266 (2015).
T. Barbier, P. Lemoine, S. Martinet, M. Eriksson, M. Gilmas, E. Hug, G. Guélou, P. Vaqueiro, A. V. Po-well, and E. Guilmeau, RSC Adv. 6, 10044 (2016).
J.-H. Pi, S.-G. Kwak, S.-Y. Kim, G.-E. Lee, and I.-H. Kim, J. Electron. Mater. 48, 1991 (2019).
A. P. Gonçalves, E. B. Lopes, M. F. Montemor, J. Monnier, and B. Lenoir, J. Electron. Mater. 47, 2880 (2018).
F. Gucci, F. D’Isanto, R. Zhang, M. J. Reece, F. Smeacetto, and M. Salvo, Materials 12, 573 (2019).
S. Battiston, F. Montagner, S. Fiameni, A. Famengo, S. Boldrini, A. Ferrario, C. Fanciulli, F. Agresti, and M. Fabrizio, J. Alloys Compd. 792, 953 (2019).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gonçalves, A.P., Lopes, E.B. Towards the Use of Cu–S Based Synthetic Minerals for Thermoelectric Applications. Semiconductors 53, 1817–1824 (2019). https://doi.org/10.1134/S1063782619130086
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063782619130086