Skip to main content
Log in

Deposition of thin Bi2Te3 and Sb2Te3 films by pulsed laser ablation

  • Fabrication, Treatment, and Testing of Materials and Structures
  • Published:
Semiconductors Aims and scope Submit manuscript

Abstract

Bi2Te3 and Sb2Te3 films were obtained by pulsed laser ablation. The films were deposited in vacuum (1 × 10−5 Torr) on single crystal substrates of Al2O3 (0001), BaF2 (111), and fresh cleavages of KCl or NaCl (001) heated to 453–523 K. The films were 10–1500 nm thick. The structures of the bulk material of targets and films were studied by X-ray diffractometry and transmission high-energy electron diffraction, respectively. Electrical properties of the films were measured in the temperature range of 77–300 K. It is shown that the films possess semiconductor properties. Several activation portions are observed in the temperature dependences of resistivity; the energies of activation portions depend on the film thickness and crystallite size.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Ioffe, Semiconductor Thermoelements and Thermoelectric Cooling (Infosearch, London, 1957).

    Google Scholar 

  2. B. M. Gol’tsman, V. A. Kudinov, and I. A. Smirnov, Semiconductor Thermoectric Materials on the Basis of Bi 2 Te 3 (Moscow, Nauka, 1972) [in Russian].

    Google Scholar 

  3. Thermoelectrics Handbook: Macro to Nano, Ed. by D. M. Rowe (Taylor and Francis, London, 2006).

    Google Scholar 

  4. R. Venkatasubramanian, E. Silvola, T. Colpitts, and B. O’Quinn, Nature 413, 597 (2001).

    Article  ADS  Google Scholar 

  5. P. G. Ganesan and V. Damodara Das, Mater. Lett. 60, 2059 (2005).

    Article  Google Scholar 

  6. R. Sathyamoorthy, J. Dheepa, and A. Subbarayan, J. Cryst. Growth 281, 563 (2005).

    Article  ADS  Google Scholar 

  7. Xingkai Duan, Junyou Yang, Wei Zhong, Wei Zhu, Siqian Bao, and Xi’an Fan, Powder Technol. 172, 63 (2007).

    Article  Google Scholar 

  8. L. M. Goncalves, C. Couto, P. Alpuim, D. M. Rowe, and J. H. Correia, Sens. Actuat. 130–131, 346 (2006).

    Article  Google Scholar 

  9. Yu. A. Boikov and V. A. Danilov, Zh. Tekh. Fiz. 78, 63 (2008) [Tech. Phys. 53, 348 (2008)].

    Google Scholar 

  10. R. Venkatasubramanian, T. Colpitts, E. Watko, M. Lamvik, and N. El-Masry, J. Cryst. Growth 170, 817 (1997).

    Article  ADS  Google Scholar 

  11. J. J. Dubowski, Chemotronics 3(7), 66 (1988).

    Google Scholar 

  12. S. V. Gaponov, V. M. Luskin, and N. N. Salashchenko, Pis’ma Zh. Tekh. Fiz. 5, 516 (1979) [Sov. Tech. Phys. Lett. 5, 210 (1979)].

    Google Scholar 

  13. Joint Committee on Powder Diffraction Standards (JCPDS), Diffraction Data Card (Am. Soc. for Testing and Materials).

  14. S. Cho, Y. Kim, A. DiVenere, G. K. Wong, J. B. Ketterson, and J. R. Meyer, Appl. Phys. Lett. 75, 1401 (1999).

    Article  ADS  Google Scholar 

  15. B. D. Cullity, Elements of X-ray Diffraction, 2nd ed. (Addison-Wesley, Reading, MA, 1978), p. 284, 366.

    Google Scholar 

  16. J. T. Cheung, in Laser-controlled Chem. Process. Surfaces Symp. (Boston, USA, 1983), p. 301.

  17. Yu. V. Goloshikhin, K. E. Mironov, and A. Ya. Polyakov, Poverkhnost’, No. 12, 12 (1991).

  18. I. O. Rudyi, I. V. Kurilo, M. S. Frugynskyj, M. Kuzma, J. Zawislak, and I. S. Virt, Appl. Surf. Sci. 154–155, 206 (2000).

    Google Scholar 

  19. I. P. Kalinkin, V. B. Aleskovskii, and A. V. Simashkevich, Epitaxial Films of II–VI Compounds (Leningr. Univ., Leningrad, 1978), p. 218.

    Google Scholar 

  20. O. Madelung, Semiconductors-Basic Data, 2nd ed. (Springer, 1996), p. 207.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Tetyorkin.

Additional information

Original Russian Text © I.S. Virt, T.P. Shkumbatyuk, I.V. Kurilo, I.O. Rudyi, T.Ye. Lopatinskyi, L.F. Linnik, V.V. Tetyorkin, A.G. Phedorov, 2010, published in Fizika i Tekhnika Poluprovodnikov, 2010, Vol. 44, No. 4, pp. 564–569.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Virt, I.S., Shkumbatyuk, T.P., Kurilo, I.V. et al. Deposition of thin Bi2Te3 and Sb2Te3 films by pulsed laser ablation. Semiconductors 44, 544–549 (2010). https://doi.org/10.1134/S1063782610040238

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063782610040238

Keywords

Navigation