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Correlation dependences in infrared spectra of metal phthalocyanines

  • Electronic and Optical Properties of Semiconductors
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Abstract

Metal-phthalocyanine (MPc) complexes CoPc, CuPc, CuPcCl15–16, CuPc(4-NO2-5-OPh)4, CuPc(4-CH2-phthalimide)4, CuPc(4-NO2-5-NHPhBr)4, PdPc, MgPc, PbPc, EuOAcPc, SmOAcPc, SmPc2, and YOAcPc were obtained and studied using IR spectroscopy. The correlation between the shift of the absorption band maximum in the range of 1100–1600 cm−1 and the atomic radius of template metal is found. It is shown that the planarity of the macrocycle of peripherally substituted CuPc can be estimated from the characteristics of the IR spectra.

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Authors and Affiliations

  1. St. Petersburg Technological Institute, Technical University, Moskovskii pr. 26, St. Petersburg, 198013, Russia

    A. V. Ziminov, S. M. Ramsh & T. A. Yurre

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi proezd 31, St. Petersburg, 119004, Russia

    V. V. Shamanin

  3. Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia

    E. I. Terukov & I. N. Trapeznikova

Authors
  1. A. V. Ziminov
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  2. S. M. Ramsh
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  3. E. I. Terukov
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  4. I. N. Trapeznikova
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  5. V. V. Shamanin
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  6. T. A. Yurre
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Additional information

Original Russian Text © A.V. Ziminov, S.M. Ramsh, E.I. Terukov, I.N. Trapeznikova, V.V. Shamanin, TA. Yurre, 2006, published in Fizika i Tekhnika Poluprovodnikov, 2006, Vol. 40, No. 10, pp. 1161–1166.

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Ziminov, A.V., Ramsh, S.M., Terukov, E.I. et al. Correlation dependences in infrared spectra of metal phthalocyanines. Semiconductors 40, 1131–1136 (2006). https://doi.org/10.1134/S1063782606100022

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  • DOI: https://doi.org/10.1134/S1063782606100022

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