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Synthesis and Spectral Properties of Octa-Substituted Phthalocyanines with 2,4,5-Trichlorophenol Moieties

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Abstract

Using the nitrile method of heating 4,5-di(2,4,5-trichlorophenoxy)phthalonitrile with magnesium and zinc acetates, and also aluminum and erbium chloride, at 200–240°C, metal complexes of the corresponding substituted phthalocyanines with magnesium, zinc, aluminum, and erbium, were synthesized. The ability of the obtained metal-phthalocyanines to dissolve in concentrated sulfuric acid, dimethylformamide, and chloroform was studied. The effect of the complexing metal on the position of the Q-band of the synthesized compounds was found.

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Funding

The work was carried out within the framework of the state task of the Ministry of Education and Science of the Russian Federation (topic no. FZZW-2020-0008) using the equipment of the Center for Collective Use of the Ivanovo State Institute of Chemical Technology (agreement no. 075-15-2021-671).

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Authors and Affiliations

  1. Research Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    S. A. Znoiko, T. V. Kustova & A. P. Elizarova

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  1. S. A. Znoiko
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  2. T. V. Kustova
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  3. A. P. Elizarova
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Correspondence to S. A. Znoiko.

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Znoiko, S.A., Kustova, T.V. & Elizarova, A.P. Synthesis and Spectral Properties of Octa-Substituted Phthalocyanines with 2,4,5-Trichlorophenol Moieties. Russ J Gen Chem 92, 2682–2689 (2022). https://doi.org/10.1134/S1070363222120180

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