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Hydrothermal Synthesis and Physicochemical Characterization of Organic-Inorganic Isopolyoxomolybdate-Based Hybrid (C6N6)4[H4Mo8O26]

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Abstract

A novel polyoxomolybdate-based organic-inorganic hybrid compound, (C6H6)4[H4Mo8O26], has been synthesized hydrothermally and characterized structurally by the elemental analysis, single crystal X-ray diffraction, thermogravimetric analysis, infrared and ultraviolet–visible spectroscopies, and cyclic voltammetry. Crystallographic data for the compound are: triclinic system, space group \(P\mathop 1\limits^\_ \), unit cell parameters a = 9.605(2)  Å, b = 9.991(3) Å, c = 10.718(3) Å, α = 83.75(2)°, β = 76.45(3)°, γ = 69.07(3)°, Z = 1. The crystal consists of the clusters β-[Mo8O26]4– and four organic molecules C6H6. Isopolymolybdate anions are connected with the organic molecules via a complex hydrogen-bonded network, which generate a three-dimensional framework.

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Authors and Affiliations

  1. Department of Chemistry, University of Monastir, Monastir, Tunisia

    M. M. Ftini, A. Chaabani & T. Boubaker

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  1. M. M. Ftini
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  2. A. Chaabani
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  3. T. Boubaker
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Correspondence to M. M. Ftini.

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Ftini, M.M., Chaabani, A. & Boubaker, T. Hydrothermal Synthesis and Physicochemical Characterization of Organic-Inorganic Isopolyoxomolybdate-Based Hybrid (C6N6)4[H4Mo8O26]. Crystallogr. Rep. 64, 1023–1029 (2019). https://doi.org/10.1134/S1063774519070058

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  • DOI: https://doi.org/10.1134/S1063774519070058

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