Skip to main content
SpringerLink
Log in

Crystal structures of 5,6-dimethyl-1,2,3,4-tetrahydro-1,10-phenanthroline and its benzene sulfonate

  • Structure of Organic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

Single crystals of 5,6-dimethyl-1,2,3,4-tetrahydro-1,10-phenanthroline (1), as well as its benzene sulfonate, i.e. (bsa) · (1H) (2) (bsaH = benzenesulfonic acid), were synthesized and characterized by elemental analysis (EA), infrared spectrometry (IR) and single crystal X-ray diffraction (SCD). The neutral molecules of 1 adopt a slipped herringbone packing mode in solid state. Whereas, the 1H+ cations in compound 2 form ion pairs with neighboring (bsa)-anions, and show a one-dimensional cross-stacking mode. Crystal data of 1: Monoclinic, space group P21/n, a = 8.2650(18), b = 10.744(2), c = 13.149(3) Å, β = 107.194(3)°, Z = 4, V = 1115.4(4) Å3, Crystal data of 2: Monoclinic, space group P21/c, a = 7.572(3), b = 10.106(4), c = 23.137(9) Å, β = 93.802(5)°, Z = 4, V = 1766.6(12) Å3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. Li, Y. Mulyana, M. Feterl, J. M. Warner, et al., Dalton. Trans. 40, 5032 (2011).

    Article  Google Scholar 

  2. S. P. Chen, Y. Guo, Q. L. Chen, et al., J. Coord. Chem. 61, 973 (2008).

    Article  Google Scholar 

  3. N. Raman and J. Joseph, Russ. J. Inorg. Chem. 55, 1064 (2010).

    Article  Google Scholar 

  4. M. Li, J. F. Xiang, S. M. et al., J. Mol. Struct. 840, 119 (2007).

    Article  ADS  Google Scholar 

  5. Q. Y. Chen, H. J. Fu, W. H. Zhu, et al., Dalton Trans. 40, 4414 (2011).

    Article  Google Scholar 

  6. F. Y. Yi, Q. P. Lin, T. H. Zhou, and J. G. Mao, Cryst. Growth Des. 10, 1788 (2010).

    Article  Google Scholar 

  7. M. A. Rizvi, N. Teshima, and G. M. Peerzada, Croat. Chem. Acta 86, 345 (2013).

    Article  Google Scholar 

  8. V. Lippolis and M. Shamsipur, J. Ind. Chem. Soc. 3, 105 (2006).

    Google Scholar 

  9. N. Shan, A. D. Bond, and W. Jones, New J. Chem. 27, 365 (2003).

    Article  Google Scholar 

  10. C. V. K. Sharma and A. Clearfield, J. Amer. Chem. Soc. 122, 4394 (2000).

    Article  Google Scholar 

  11. S. M. Wu, S. P. Chen, M. Li, et al., Cryst. Eng. Comm. 9, 907 (2007).

    Article  Google Scholar 

  12. C. Metallinos, F. B. Barrett, J. L. Chaytor, and M. E. A. Heska, Org. Lett. 6, 3641 (2004).

    Article  Google Scholar 

  13. I. Eckhard, R. Fielden, and L. Summers, Aust. J. Chem. 28, 1149 (1975).

    Article  Google Scholar 

  14. P. C. Keller, R. L. Marks, and J. V. Rund, Polyhedron 2, 595 (1983).

    Article  Google Scholar 

  15. B. C. Ranu, U. Jana, and A. Sarkar, Synthetic Commun. 28, 485 (1998).

    Article  Google Scholar 

  16. A. Srikrishna, T. Jagadeeswar Reddy, and R. Viswajanani, Tetrahedron 52, 1631 (1996).

    Article  Google Scholar 

  17. C. Bianchini, V. Dal Santo, A. Meli, et al., Inorg. Chim. Acta 361, 3677 (2008).

    Article  Google Scholar 

  18. S. P. Chen, P. Deng, C. F. Yuan, and L. J. Yuan, Cryst. Eng. Comm. 15, 1414 (2013).

    Article  Google Scholar 

  19. G. M. Sheldrick, Acta Cryst. A 64, 112 (2008).

    Article  Google Scholar 

  20. C. F. Macrae, P. R. Edgington, P. McCabe, et al., J. Appl. Cryst. 39, 453 (2006).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Lab of New Processing Technology for Nonferrous Metals & Materials, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin, 541004, P. R. China

    J. Deng, H. P. Su & S. P. Chen

Authors
  1. J. Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. P. Su
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. P. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. P. Chen.

Additional information

The article is published in the original.

These authors contributed equally to this work.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Deng, J., Su, H.P. & Chen, S.P. Crystal structures of 5,6-dimethyl-1,2,3,4-tetrahydro-1,10-phenanthroline and its benzene sulfonate. Crystallogr. Rep. 59, 1051–1056 (2014). https://doi.org/10.1134/S1063774514080021

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774514080021

Keywords

Search

Navigation