Abstract
This study is focused on synthesizing environmentally friendly nano-probes for rapid and sensitive detection of H2O2. Biogenic manganese oxide nanoparticles were prepared and capped with two different types of nitrogen doped carbon dots. Nanocomposites are designated as NC1 (semicarbazide hydrochloride as a dopant source) and NC2 (urea as a dopant source). Synthesized nanocomposites (NC1 and NC2) were characterized by different techniques. UV-visible spectra depicted peaks at 298 nm (NC1) and 299 nm (NC2). FTIR confirmed the presence of different functional groups at the surface of nanocomposites. XRD showed the amorphous carbon structure of nanocomposites with particle size of 7 nm (NC1) and 6 nm (NC2). Raman spectra showed the graphitic carbon structure. In both cases, D and G bands were observed with ID/IG ratio equal to 0.76 for NC1 and 0.16 for NC2. NC1 depicted linearity for the concentration range of 10–40 µM with LOD and LOQ of 7 and 24 µM, respectively, while NC2 exhibited linearity over the concentration range of 50–80 µM with LOD of 12 µM and LOQ of 40 µM. Percentage recoveries for spiked samples were calculated to be 99.8–101.8 and 98.5–99.1% for NC1 and NC2, respectively.
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REFERENCES
Li, S., Li, H., Chen, F., Liu, J., Zhang, H., Yang, Z., and Wang, B., Dyes Pigm., 2016, vol. 125, p. 64.
Teodoro, R.B.K., Migliorini, L.F., Christinelli, A.W., and Correa, S.D., Carbohydr. Polym., 2019, vol. 212, p. 235.
Guan, F.J., Huang, Z.N., Zou, J., Jiang, Y.X., Peng, M.D., and Yu, G.J., Ecotoxicol. Environ. Saf., 2020, vol. 190, 110123. https://doi.org/10.1016/j.ecoenv.2019.110123
Lu, J., Zhang, H., Li, S., Guo, S., Shen, L., Zhou, T., and Zhang, Y., Inorg. Chem., 2020, vol. 59, no. 5, p. 3152.
Mahdavi, B., Paydarfard, S., Zangeneh, M.M., Goorani, S., Seydi, N., and Zangeneh, A., Appl. Organomet. Chem., 2020, vol. 34, no. 1, p. 1.
Dawadi, S., Gupta, A., Khatri, M., Budhathoki, B., Lamichhane, G., and Parajuli, N., Bull. Mater. Sci., 2020, vol. 43, p. 277. https://doi.org/10.1007/s12034-020-02247-8
Chen, J., Shu, Y., Li, H., Xu, Q., and Hu, X., Talanta, 2018, vol. 189, p. 254.
Liu, H., Ma, H., Xu, H., Wen, J., Huang, Z., Qiu, Y., and Gu, C., Anal. Bioanal. Chem., 2019, vol. 411, no. 1, p. 129.
Jones, M.R. and Lee, K., Microchem. J., 2019, vol. 147, p. 1021.
Liu, Q., Chen, P., Xu, Z., Chen, M., Ding, Y., Yue, K., and Xu, J., Sens. Actuators, B, 2017, vol. 251, p. 339.
Mercante, A.L., Facure, M.H.M., Sanfelice, C.R., Migliorini, L.F., Mattoso, C.H.L., and Correa, S.D., App-l. Surf. Sci., 2017, vol. 407, p. 162.
McCurdy, Jr. H.W., and Bell, F.H., Talanta, 1966, vol. 13, no. 7, p. 925.
Guo, Z., Shen, X.H., and Li, L., Microchim. Acta, 1999, vol. 131, nos. 3–4, p. 171.
Christé, S., da Silva, E.G.C.J., and da Silva, P.L., Materials, 2020, vol. 13, no. 3, p. 23.
Szmyt, P.M., Buszewski, B., and Kopciuch, G.R., Mater. Chem. Phys., 2020, vol. 2019, p. 122484. https://doi.org/10.1016/j.matchemphys.2019.122484
Ayyanar, M. and Subash-Babu, P., Asian Pac. J. Trop. Biomed., 2012, vol. 2, no. 3, p. 240.
Kumar, V., Yadav, C.S., and Yadav, K.S., J. Chem. Technol. Biotechnol., 2010, vol. 85, no. 10, p. 1301.
Pai, J.R., Valder, B., Palatty, L.P., Shivashankara, R.A. and Baliga, S.M., in Bioactive Food as Dietary Interventions for Liver and Gastrointestinal Disease, Watson, R.R. and Preedy, R.V., Eds., London: Academic, 2013, p. 369.
Bitencourt, R.E.P., in Diabetes, Preedy, R.V., Ed., London: Academic, 2020, p. 343.
Joshi, N.C., Siddiqui, F., Salman, M., and Singh, A., Asian Pacific J. Health Sci., 2020, vol. 7, no. 3, p. 27
Bano, D., Chandra, S., Yadav, K.P., Singh, K.V., and Hasan, H.S., J. Photochem. Photobiol. A: Chem., 2020, vol. 398, p. 112558. https://doi.org/10.1016/j.jphotochem.2020.112558
Raja, P.M.V. and Barron, A.R., Nature, 1934, vol. 134, no. 3384, p. 366.
Verma, G. and Mishra, M., World J. Pharm. Res., 2018, vol. 7, no. 11, p. 1170.
Patel, P.J. and Parsania, H.P., in Biodegradable and Biocompatible Polymer Composites: Processing, Properties and Applications, Shimpi, N.G., Ed., London: Woodhead, 2017, p. 55.
Wilson, N.H., An Approach to Chemical Analysis, New York: Pergamon, 1966, p. 222.
Dutta, A., Fourier Transform Infrared Spectroscopy, Thomas, S., Thomas, R., Zachariah, K.A., and Mishra, R.K., Eds., Amsterdam: Elsevier, 2017, p. 73.
Zhu, Z., Lin, X., Wu, L., Zhao, C., Zheng, Y., Liu, A., and Lin, L., Sens. Actuators, B, 2018, vol. 274, p. 609.
Garg, D., Mehta, A., Mishra, A., and Basu, S., Spectrochim. Acta, Part A, 2018, vol. 192, p. 411.
Liu, X., Liu, J., Zheng, B., Yan, L., Dai, J., Zhuang, Z., and Xiao, D., New J. Chem., 2017, vol. 41, no. 19, p. 10607.
Gong, X., Lu, W., Paau, C.M., Hu, Q., Wu, X., Shuang, S., and Choi, F.M.M., Anal. Chim. Acta, 2015, vol. 861, p. 74.
Liu, Z., Cai, X., Lin, X., Zheng, Y., Wu, Y., Chen, P., Lin, L., Shaohuang, W., and Lin, X., Anal. Methods, 2016, vol. 8, no. 11, p. 2366.
Edison, I.J.N.T., Atchudan, R., Sethuraman, G.M., Shim, J.J., and Lee, R.Y., J. Photochem. Photobiol., B, 2016, vol. 161, p. 154.
Buzea, C. and Pacheco, I., in EMR/ESR/EPR Spectroscopy for Characterization of Nanomaterials, Shukla, A., Ed., New Delhi: Springer, 2017, p. 3
Chandrasekaran, P., Arul, V., and Sethuraman, G.M., J. Fluoresc., 2020, vol. 30, no. 1, p. 103.
Mewada, A., Pandey, S., Shinde, S., Mishra, N., Oza, G., Thakur, M., and Sharon, M., Mater. Sci. Eng., C, 2013, vol. 33, no. 5, p. 2914.
Wang, Q., Pang, H., Dong, Y., Chi, Y., and Fu, F., Microchim. Acta, 2018, vol. 185, no. 6, p. 291.
Mohammed, A. and Abdullah, A., Proc. Int. Conf. on Hydraulics and Pneumatics, Băile Govora, Romania, 2018, p. 7.
Zheng, J., Song, D., Chen, H., Xu, J., Alharbi, S.N., Hayat, T., and Zhang, M., Chin. Chem. Lett., 2020, vol. 31, no. 5, p. 1109.
Feng, Y., Li, Y., Yu, S., Yang, Q., Tong, Y., and Ye, C.B., Analyst, 2021, vol. 146, no. 16, p. 5135.
Vigil, D.D.M., Delgado, P.F., Martnez, C.V., and Ortiz, L.A., Int. J. Chem. React. Eng., 2008, vol. 6, no. 1. https://doi.org/10.2202/1542-6580.1616
Zhang, Y., Zhang, J.Y., Xia, D.X., Hou, Q.X., Feng, T.C., Wang, X.J., and Deng, L., Chin. Chem. Lett., 2013, vol. 24, no. 12, p. 1053.
Chen, Z., Zhang, C., Wu, Q., Li, K., and Tan, L., Sens. Actuators, B, 2015, vol. 220, p. 314.
Niu, T., Deng, X., Wang, R., and Zhou, C., Mater. Today Chem., 2018, vol. 7, p. 35.
Di, W., Zhang, X., and Qin, W., Appl. Surf. Sci., 2017, vol. 400, p. 200.
Huang, Z., Zheng, L., Feng, F., Chen, Y., Wang, Z., Lin, Z., and Weng, S., Sensors, 2018, vol. 18, no. 8, p. 2525. https://doi.org/10.3390/s18082525
Zhang, L. and Li, L., Anal. Methods, 2016, vol. 8, no. 37, p. 6691.
Winterbourn, C.C., Toxicol. Lett., 1995, vols. 82–83, p. 969.
Hu, L., Yuan, Y., Zhang, L., Zhao, J., Majeed, S., and Xu, G. Anal. Chim. Acta, 2013, vol. 762, p. 83.
Dong, Y., Zhang, J., Jiang, P., Wang, G., Wu, X., Zhao, H., and Zhang, C., New J. Chem., 2015, vol. 39, no. 5, p. 4141.
Zhang, L., Hai, X., Xia, C., Chen, X. W., and Wang, J. H. Sens. Actuators, B, 2017, vol. 248, p. 374.
Honarasa, F., Kamshoori, F. H., Fathi, S., and Motamedifar, Z., Microchim. Acta, 2019, vol. 186, no. 4, p. 234. https://doi.org/10.1007/s00604-019-3344-6
Shi, W., Wang, Q., Long, Y., Cheng, Z., Chen, S., Zheng, H., and Huang, Y., Chem. Commun., 2011, vol. 47, no. 23, p. 6695.
Ge, J., Xing, K., Geng, X., Hu, Y.L., Shen, X.P., Zhang, L., and Li, Z.H., Microchim. Acta, 2018, vol. 185, no. 12, p. 559. https://doi.org/10.1007/s00604-018-3099-5
Bakre, V.P., Tilve, G.S., and Shirsat, N.R., Arab. J. Chem., 2020, vol. 13, no. 11, p. 7637.
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Zaib, M., Safdar, A., Shahzadi, T. et al. Enrichment of MnO2 Nanoparticles with Different N-Doped Carbon Dots as a Robust H2O2 Sensor: a Comparative Study. J Anal Chem 78, 704–717 (2023). https://doi.org/10.1134/S1061934823060126
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DOI: https://doi.org/10.1134/S1061934823060126