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Effect of a solvent on the parameters of the analytical signal, detection limit, and analytical range of the determination in analytical thermal lens spectrometry

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Abstract

The effect of the main parameters of the solvents (water, acetone, methanol, ethanol, acetonitrile, dimethyl sulfoxide, dichloromethane, toluene, and chloroform) that are most frequently used in the analytical practice on the characteristics of the thermal lens effect (increase in temperature because of optical heating and in the size of the region involved in heating) and on the detection limit and the lower determination limit of the thermal lens determination was considered, and the criteria of the selection of the medium for thermal lens experiments were discussed. It was demonstrated that the gain in these characteristics of the thermal lens determination in the given medium in comparison with the aqueous medium does not necessarily coincide with the strength of the thermooptical effect in this medium. It was demonstrated that the optimum conditions of measurements in the thermal lens detection are controlled not only by the absorption of the analyte and the reagents, but also by the intrinsic absorption of the solvent. Recommendations were given on the selection of the solvent for analytical thermal lens spectrometry.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Leninskie gory, Moscow, 119991, Russia

    M. A. Proskurnin, S. N. Bendrysheva & V. V. Kuznetsova

  2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia

    A. A. Zhirkov & B. K. Zuev

Authors
  1. M. A. Proskurnin
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  2. S. N. Bendrysheva
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  3. V. V. Kuznetsova
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  4. A. A. Zhirkov
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  5. B. K. Zuev
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Original Russian Text © M.A. Proskurnin, S.N. Bendrysheva, V.V. Kuznetsova, A.A. Zhirkov, B.K. Zuev, 2008, published in Zhurnal Analiticheskoi Khimii, 2008, Vol. 63, No. 8, pp. 813–823.

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Proskurnin, M.A., Bendrysheva, S.N., Kuznetsova, V.V. et al. Effect of a solvent on the parameters of the analytical signal, detection limit, and analytical range of the determination in analytical thermal lens spectrometry. J Anal Chem 63, 741–750 (2008). https://doi.org/10.1134/S1061934808080066

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  • DOI: https://doi.org/10.1134/S1061934808080066

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