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Studies of kinetics of indirect in situ electrocatalytic oxidation of aliphatic alcohols to carboxylic acids by active forms of oxygen

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Abstract

The model reagents substrates, 1-butanol and 1-nonanol are used to study the general kinetic regularities of indirect electrocatalytic oxidation of aliphatic alcohols on conventional (Pb/PbO2) and catalytically active (oxide–hydroxide–nickel) electrodes to the corresponding carboxylic acids (butyric and pelargonic) at the participation of active oxygen forms (AOF) generated in situ from O2, H2O2, and H2O. It is found that the kinetics of the alcohol oxidation reaction correspond to the pseudo first order when the studied AOF generation schemes are used. The effect of the nature of electrode materials on the kinetic regularities of oxidation of aliphatic alcohols to the corresponding carboxylic acids is established for the aspects pointing to the presence of different active forms of bound oxygen determining the possible reaction routes. On the basis of the obtained results, the main possible oxidation routes with the participation of active oxygen generated in situ are considered.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, building 24, 660036, Krasnoyarsk, Russia

    A. M. Kosheleva, N. G. Maksimov, G. V. Kornienko & V. L. Kornienko

  2. Siberian State Technological University, prospect Mira 82, 660049, Krasnoyarsk, Russia

    G. V. Kornienko

Authors
  1. A. M. Kosheleva
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  2. N. G. Maksimov
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  3. G. V. Kornienko
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  4. V. L. Kornienko
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Correspondence to V. L. Kornienko.

Additional information

Presented at the 18th AllRussian Conference on Organic Electrochemistry, Tambov, September 15–19, 2014.

Original Russian Text © A.M. Kosheleva, N.G. Maksimov, G.V. Kornienko, V.L. Kornienko, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 11, pp. 1216–1222.

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Kosheleva, A.M., Maksimov, N.G., Kornienko, G.V. et al. Studies of kinetics of indirect in situ electrocatalytic oxidation of aliphatic alcohols to carboxylic acids by active forms of oxygen. Russ J Electrochem 51, 1079–1085 (2015). https://doi.org/10.1134/S1023193515110075

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  • DOI: https://doi.org/10.1134/S1023193515110075

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