Skip to main content
SpringerLink
Log in

The interaction between hydrogen peroxide and metal oxides: EPR investigations

  • Published:
Applied Magnetic Resonance Aims and scope Submit manuscript

Abstract

The interaction of hydrogen peroxide with various metal oxides has been followed by EPR in the aim of investigating the paramagnetic species formed along the complex processes of H2O2 decomposition and interaction with the oxide. Data are reported about three systems (MgO, ZrO2 and Me2+/Y zeolite) which are representative of three classes of oxides (insulators, semiconductors and aluminosilicate molecular sieves). Several radical species have been put into evidence in the various cases. The superoxide O −2 ion has been observed in all cases while in the case of MgO also the OH radical and the O− radical ion have been identified. In the case of Zn2+/Y zeolite, beside the superoxide radical anion, a new signal is observed which shows up upon treating the sample at 640 K and which is preliminarily assigned to a species in the triplet state in the zeolitic cavity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Schirmann J.P., Delavarenne S.Y.: Hydrogen Peroxide in Organic Chemistry. Paris: Edition et Documentation Industrielle 1979.

    Google Scholar 

  2. Milas N.A., Sussman S.: J. Am. Chem. Soc.58, 1302 (1936)

    Article  Google Scholar 

  3. Sheldon A., Kochi J.K.: Metal Catalysed Oxidation of Organic Compounds. New York: Academic Press 1981.

    Google Scholar 

  4. Roussel M., Mimoun H.: J. Org. Chem.45, 4387 (1980)

    Article  Google Scholar 

  5. Notari B. in: Proceedings International Symposium Innovation in Zeolite Material Science (Grobet P.J.et al., eds.) Nieuwport, Belgium 1987; Studies in Surface Science and Catalysis vol. 37, p. 413. Amsterdam: Elsevier 1988.

    Chapter  Google Scholar 

  6. Clerici M.G., Bellussi G., Romano U.: J. Catal.129, 159 (1991)

    Article  Google Scholar 

  7. Haber J., Bielanski A.: Oxygen in Catalysis. New York: Marcel Dekker 1991.

    Google Scholar 

  8. Che M., Tench A.J.: Adv. Catal.31, 77 (1982)

    Article  Google Scholar 

  9. Che M., Tench A.J.: Adv. Catal.32, 1 (1983)

    Article  Google Scholar 

  10. Che M., Giamello E., Tench A.J.: Colloid and Surfaces13, 231 (1985)

    Article  Google Scholar 

  11. Giamello E., Che M.: Electron Magnetic Resonance of Disordered Systems (EMARDIS' 91) (Yordanov N.D., ed.), p. 112. World Scientific 1991.

  12. Iyengar R.D., Subba Rao V.V.: J. Phys. Chem.75, 3089 (1971)

    Article  Google Scholar 

  13. Arutyunyan A.Zh., Grigoryan G.L., Nalbandyan A.B.: Kinet. Katal.26, 785 (1985)

    Google Scholar 

  14. Arutyunyan A.Zh., Gazaryan K.G., Garibyan T.A., Grigoryan G.L., Nalbandyan A.B.: Kinet. Katal..29, 754 (1988)

    Google Scholar 

  15. Amorelli A., Evans C.J., Rowlands C.C.: J. Chem. Soc., Faraday Trans. I.84, 1723 (1988)

    Article  Google Scholar 

  16. Klissursky D., Hadjiivanov K., Kantcheva M., Gyurova L.: J. Chem. Soc., Faraday Trans.86, 385 (1990)

    Article  Google Scholar 

  17. Giamello E., Fubini B., Volante M., Costa D.: Colloids and Surfaces45, 155 (1990)

    Article  Google Scholar 

  18. Bellussi G., Carati A., Clerici M.G., Maddinelli G., Millini R.: J. Catal.133, 220 (1992)

    Article  Google Scholar 

  19. Hart A.B., McFayden J., Ross R.A.: Trans. Faraday Soc.,59, 1458 (1963)

    Article  Google Scholar 

  20. Murphy B.J., Ross R.A.: J. Chem. Soc. (A)1968, 2044.

  21. Arutyunyan A.Zh., Grigoryan G.L., Nalbandyan A.B.: Kinet. Katal.27, 1352 (1986)

    Google Scholar 

  22. Egerton T.A., Stone F.S.: J. Chem. Soc., Faraday Trans. I.69, 22 (1973)

    Article  Google Scholar 

  23. Giamello E., Calosso L., Fubini B., Geobaldo F.: J. Phys. Chem.97, 5735 (1993)

    Article  Google Scholar 

  24. Brivati J.A., Symons M.C.R., Tinling D.J.A., Wardale H.W., Williams D.O.: Trans. Faraday Soc.63, 2112 (1967)

    Article  Google Scholar 

  25. Brivati J.A., Symons M.C.R., Tinling D.J.A., Williams D.A.: J. Chem. Soc. (A)1969, 719.

  26. Dibdin G.H.: Trans. Faraday Soc..63, 2098 (1967)

    Article  Google Scholar 

  27. Box H.C., Budzinski E.E., Lilga K.T., Freund H.G.: J. Chem. Phys..53, 1059 (1970)

    Article  ADS  Google Scholar 

  28. Gunter T.E.: J. Chem. Phys..46, 3818 (1967)

    Article  ADS  Google Scholar 

  29. Toriyama K., Iwasaki M.J.: Chem. Phys.55, 1890 (1971)

    ADS  Google Scholar 

  30. Riederer H., Hüttermann J., Boon P.J., Symons M.C.R.: J. Magn. Reson.54, 54 (1983)

    Google Scholar 

  31. Tench A.J.: Surf. Sci..25, 624 (1971)

    Article  ADS  Google Scholar 

  32. Giamello E., Volante M., Fubini B., Geobaldo F., Morterra C.: Mater. Chem. Phys.29, 379 (1991)

    Article  Google Scholar 

  33. Kanzig W., Cohen M.H.: Phys. Rev. Lett..3, 509 (1959)

    Article  ADS  Google Scholar 

  34. Giamello E., Ugliengo P., Garrone E.: J. Chem. Soc. Faraday Trans. I85, 1373 (1989)

    Article  Google Scholar 

  35. Morterra C., Giamello E., Orio L., Volante M.: J. Phys. Chem..94, 3111 (1990)

    Article  Google Scholar 

  36. Chamulitrat W., Kevan L.: J. Phys. Chem..89, 4989 (1985)

    Article  Google Scholar 

  37. Brustolon M., Pasimeni L., Corvaja C.: J. Chem. Soc. Dalton Transactions1980, 604.

  38. Chao C., Lunsford J.H.: J. Chem. Phys..57, 2890 (1972)

    Article  ADS  Google Scholar 

  39. Unruh W.P., Chen Y., Abraham M.M.: Phys. Rev. Lett..30, 446 (1973)

    Article  ADS  Google Scholar 

  40. Rubio O.J., Tohver H.T., Chen Y., Abraham M.M.: Phys. Rev.B14, 5466 (1976)

    ADS  Google Scholar 

  41. Ono Y., Matsumura T., Kitajima N., Fukuzumi S.: J. Phys. Chem..81, 1307 (1977)

    Article  Google Scholar 

  42. Baxendale J.H.: Adv. Catal.4, 31 (1952)

    Article  Google Scholar 

  43. Haber F., Weiss J.: Proc. Roy. Soc. (London)A147, 332 (1934)

    ADS  Google Scholar 

  44. Arutyunyan A.Zh., Grigoryan G.L., Nalbandyan A.B.: Kinet. Katal.28, 1121 (1987)

    Google Scholar 

  45. Schwab J.J., Brune W.H., Anderson J.G.: J. Phys. Chem.93, 1030 (1989)

    Article  Google Scholar 

  46. Bielsky B.H.J., Cabelli D.E., Arudi R.L., Ross A.B.: J. Phys. Chem. Ref. Data14, 1041 (1985)

    ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, Via P. Giuria 7, 10125, Torino, Italy

    E. Giamello, P. Rumori, F. Geobaldo, B. Fubini & M. C. Paganini

Authors
  1. E. Giamello
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Rumori
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Geobaldo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. Fubini
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. C. Paganini
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Giamello, E., Rumori, P., Geobaldo, F. et al. The interaction between hydrogen peroxide and metal oxides: EPR investigations. Appl. Magn. Reson. 10, 173–192 (1996). https://doi.org/10.1007/BF03163108

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03163108

Keywords

Search

Navigation