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Effect of the structure of calix[4]arene-para-sulfonic acid on its transport properties

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Abstract

The effect of a change in the ambient temperature and humidity on the behavior of calix(4)arene-para-sulfonic acid was studied. For the calixarene under study, at least two stable hydrates were observed: tetra- and octahydrate. The number of water molecules in the crystalline hydrate of the acid was confirmed by simultaneous thermal analysis data and the shape of the IR spectra and diffraction patterns. The change in the composition of the hydrate from n = 4 to n = 20 affected the conductivity but slightly; in the region of phase transitions between the hydrates, the activation energy of conductivity changed abruptly.

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Authors and Affiliations

  1. The Institute of Problems of Chemical Physics, Russian Academy of Sciences, Moscow oblast, Chernogolovka, 142432, Russia

    L. V. Shmygleva, E. A. Sanginov, R. R. Kayumov, A. E. Ukshe & Yu. A. Dobrovol’skii

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  1. L. V. Shmygleva
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  2. E. A. Sanginov
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  3. R. R. Kayumov
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  4. A. E. Ukshe
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  5. Yu. A. Dobrovol’skii
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Correspondence to L. V. Shmygleva.

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Original Russian Text © L.V. Shmygleva, E.A. Sanginov, R.R. Kayumov, A.E. Ukshe, Yu.A. Dobrovol’skii, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 5, pp. 540–544.

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Shmygleva, L.V., Sanginov, E.A., Kayumov, R.R. et al. Effect of the structure of calix[4]arene-para-sulfonic acid on its transport properties. Russ J Electrochem 51, 468–472 (2015). https://doi.org/10.1134/S1023193515050134

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  • DOI: https://doi.org/10.1134/S1023193515050134

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