Abstract
The heat resistance of adhesive joints of SVM heterocyclic aramid fibers and cyanoacrylate glue has been studied based on the adhesion failure temperature in an adhesion cell formed by a loop tightened into a knot. For the first time, data on the heat resistance of adhesive joints of fibers with a polymer matrix under static load with constant shear stress have been obtained. Using the example of two types of glue, the influence of filler in the glue and fibers on the glass transition temperature of polycyanoacrylate and the heat resistance of the adhesive joint is shown. The activation energy of adhesion failure was calculated, and the dependence of the thermal stability of the adhesive joint on the shear stress was shown to be of the Arrhenius type.
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ACKNOWLEDGMENTS
The authors express their gratitude to D.Yu. Yur’ev (Mendeleev University of Chemical Technology) for recording the IR spectra of polyisocyanoacrylates.
The work was carried out using the testing equipment of the Shared-Use Center “Analytical Center for Problems of Advanced Oil Refining and Petroleum Chemistry” at the Topchiev Institute of Petrochemical Synthesis.
Funding
This work was supported by the Russian Science Foundation, Grant number 23-69-10001.
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Kotomin, S.V., Golubev, Y.V., Gurov, A.A. et al. Heat Resistance of Adhesive Joints of Heterocyclic Aramid Fibers under Static Load. Polym. Sci. Ser. A 65, 831–840 (2023). https://doi.org/10.1134/S0965545X23600667
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DOI: https://doi.org/10.1134/S0965545X23600667