Abstract
Mono-and bis(methylthiomethyl) substituted derivatives of cyclopentanone and cyclohexanone were obtained on the basis of natural methylmercaptan via the alkylthiomethylation of ketones, and these derivatives were converted into the corresponding γ-hydroxysulfides and ketosulfones via reduction with sodium borohydride and oxidation with hydrogen peroxide, respectively.
Similar content being viewed by others
References
A. D. Ulendeeva, L. A. Baeva, E. G. Galkin, et al., Neftekhimiya 38, 214 (1998) [Pet. Chem. 38, 197 (1998)].
A. D. Ulendeeva, L. A. Baeva, O. R. Valiullin, et al., Neftekhimiya 46, 139 (2006) [Pet. Chem. 46, 122 (2006)].
A. D. Ulendeeva, L. A. Baeva, T. S. Nikitina, et al., in Proceedings of III All-Russia Scientific INTERNET Conference “Integration of Science and Higher Education in the Field of Bioorganic and Organic Chemistry and Mechanics of Multiphase Systems”, Ufa, 2004, p. 60.
V. V. Potapov, R. A. Khisamutdinov, Yu. I. Murinov, et al., Zh. Prikl. Khim. (St. Petersburg) 74, 1070 (2001).
N. K. Algebraistova, N. V. Gudkova, E. A. Alekseeva, et al., RU Patent No. 2 185 249, Byull. Izobret., No. 20 (2002).
N. A. Gafarov, V. M. Kushnarenko, D. E. Bugai, et al., Corrosion Inhibitors (Khimiya, Moscow, 2002) [in Russian].
I. A. Rubinshtein, Z. A. Kleimenova, and E. P. Sobolev, in Methods for Analysis of Petroleum Organic Compounds, Their Mixtures and Derivatives (Moscow, 1960), p. 74.
Z. Jedlinski, A. Misiotek, W. Glowkowski, et al., Tetrahedron 46, 3547 (1990).
V. P. Krivonogov, N. G. Afzaletdinova, Yu. I. Murinov, et al., Zh. Prikl. Khim. (St. Petersburg) 71, 828 (1998).
I. Paterson and I. Fleming, Tetrahedron Lett., No. 11, 995 (1979).
I. Paterson, Tetrahedron 44, 4207 (1988).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.A. Baeva, A.D. Ulendeeva, D.D. Arslanova, O.V. Shitikova, E.G. Galkin, N.K. Lyapina, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 5, pp. 390–394.
Rights and permissions
About this article
Cite this article
Baeva, L.A., Ulendeeva, A.D., Arslanova, D.D. et al. Thio derivatives of cyclopentanone and cyclohexanone. Pet. Chem. 48, 393–397 (2008). https://doi.org/10.1134/S0965544108050101
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965544108050101