Abstract
A technology of producing a high-quality hafnium–nickel GfNi10 master alloy is developed: it is produced in a vacuum arc furnace with a nonconsumable electrode using a preliminary annealed pressed electrolytic hafnium powder. The total content of impurities and oxygen and nitrogen gases in the master alloy is found to be substantially lower than that in a serial GFN-10 master alloy. The character of interaction of the master alloy with the nickel melt during vacuum induction melting of the new VZhM200 cast nickel superalloy shows that, in contrast to a GFN-10 master alloy, the GfNi10 master alloy produced in VIAM gives no melt splashes during the introduction of the master alloy; this increases the assimilation of hafnium. The chemical composition and mechanical properties of a serial VKNA-1VR alloy and the new VZhL125 nickel superalloy melted with the developed master alloy correspond to the requirements of specifications for these alloys. In addition, high hafnium assimilation and low contents of gas impurities are ensured.
REFERENCES
S. M. Kozlova, ““Superjet-100”: under the wing of cooperation”, Mir Transporta, No. 2 (18), 50–53 (2007).
M. O. Tolboev, “Civil aviation of Russia: before and after Superjet,” Standarty i Kachestvo, No. 7, 80–82 (2019).
I. V. Bazikova, “Main challenges of “Sukhoi Superjet 100” project,” Vestn. Univ., No. 6, 48–54 (2018).
D. Yu. Duritsyn and V. P. Sokolyanskii, “Results of fire prevention operations for amphibious airplane Be-200 in 2004–2007,” Polet. Obshcherossiiskii Nauch.-Tekhn. Zh., No. 12, 35–37 (2008).
A. V. Tarasova, “Amphibian Beriev Be-200 “Altair,” Molodezhn. Nauch.-Tekhn. Vestn., No. 12, 4 (2014).
A. I. Tikhonov and A. A. Sazonov, “Innovative Russian aircraft Sukhoi Superjet 100 as a vector of development of aircraft engineering for future,” Ekonomika i Predprinimat., No. 7 (96), 289–292 (2018).
P. G. Min, V. E. Vadeev, and V. V. Kramer, “Development of a new VZhM200 nickel superalloy and its production technology for directional solidification casting of working blades of advanced engines,” Aviats. Mater. Tekhnol., No. 3 (64), 2 (2021) URL: http:// www.journal.viam.ru. https://doi.org/10.18577/2713-0193-2021-0-3-11-18
O. G. Ospennikova, O. A. Bazyleva, E. G. Arginbaeva, A. V. Shestakov, and E. Yu. Turenko, “Development of intermetallic nickel alloys and composite materials based on them,” Vestn. Bauman MGTU, Ser. Mashinostr., No. 3, 75–89 (2017).
E. N. Kablov, O. G. Ospennikova, and O. A. Bazyleva, “Materials for highly heat-loaded parts of gas-turbine engines,” Vestn. Bauman MGTU, Ser. Mashinostr., No. SP2, 13–19 (2011).
Ch. T. Sims, N. S. Stoloff, and U. K. Khagel, Superalloys II: High-Temperature Materials for Aerospace and Industrial Power Plants (Metallurgiya, Moscow, 1995), pp. 160–162.
P. S. Kindyakov, B. G. Korshunov, P. I. Fedorov, and I. P. Kislyakov, in Chemistry and Technology of Rare and Scattered Elements. Part II (Vyssh. Shkola, Moscow, 1976), pp. 352–354.
S. S. Korovin, V. I. Bukin, P. I. Fedorov, and A. M. Reznik, in Rare and Scattered Elements. Chemistry and Technology. Book II (MISiS, Moscow, 2003), pp. 196–198.
E. N. Kablov, “Innovative developments of FSUE VIAM SRC RF for the realization of Strategic directions of development of materials and their processing technologies for a period of to 2030”, Aviats. Mater. Tekhnol., No. 1 (34), 3–33 (2015). https://doi.org/10.18577/2071-9140-2015-0-1-3-33
N. P. Lyakishev, O. A. Bannykh, L. L. Rokhlin, et al., in Phase Diagrams of Binary Metallic Systems: A Handbook (Mashinostroenie, Moscow, 1997), Vol. 2, pp. 885–889.
“Preparation method of master alloys in a vacuum arc furnace with nonconsumable electrode,” RF Patent 2734220, Byull. Izobret., No. 23 (2020).
F. N. Karachevtsev, A. V. Alekseev, A. F. Letov, and R. M. Dvoretskov, “Plasma analysis methods of element chemical composition of alloys,” Aviats. Mater. Tekhnol., No. S, 483–497 (2017). https://doi.org/10.18577/2071-9140-2017-0-S-483-497
E. N. Kablov, V. V. Sidorov, D. E. Kablov, and P. G. Min, “Metallurgical foundations for ensuring the high quality of single-crystal nickel superalloys,” Aviats. Mater. Tekhnol., No. S, 55–71 (2017). https://doi.org/10.18577/2071-9140-2017-0-S-55-71
D. E. Kablov, V. V. Sidorov, P. G. Min., Yu. A. Puchkov, “Effect of surface-active impurities and lanthanum addition on the structure and properties of a single-crystal ZhS36 nickel superalloy,” Trudy VIAM, No. 4 (52), 02 (2017). https://doi.org/10.18577/2307-6046-2017-0-4-2-2
P. G. Min, V. V. Sidorov, and V. E. Vadeev, “Behavior of impurities and lanthanum during directional solidification of single-crystal nickel superalloys,” Trudy VIAM, No. 7 (55), 4 (2017). https://doi.org/10.18577/2307-6046-2017-0-7-4-4
P. G. Min, D. E. Kablov, V. V. Sidorov, and V. E. Vadeev, “Effect of impurity sulfur, phosphorus, and silicon on the structure and properties of single-crystal nickel superalloys,” Materialoved., No. 8, 13–18 (2018).
ACKNOWLEDGMENTS
The study was performed using equipment available in the Collective Access Center for Climatic Tests in the National Research Centre Kurchatov Institute–VIAM.
Funding
The study was performed in terms of complex scientific direction 10 “Energy efficient, resource-saving, and additive production technologies of parts, semi-finished products, and constructions (Strategic directions for the development of materials and their recycling technologies for a period of to 2030)” [13].
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Translated by N. Kolchugina
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Min, P.G., Pitelin, N.S. & Vadeev, V.E. Development of a Technology of Production of a Hafnium–Nickel Master Alloy in a Vacuum Arc Furnace for the Alloying of Cast Nickel Superalloys. Russ. Metall. 2023, 2022–2029 (2023). https://doi.org/10.1134/S0036029523700052
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036029523700052