Abstract
Mixed-ligand neodymium(III) complexes with carboxylic acids and nitrogen- and phosphorus-containing neutral ligands, which luminesce in the near-IR region, are studied by luminescence and X-ray photoelectron spectroscopies. It is found that coordination of neutral ligands through the nitrogen donor atom leads to an increase in the electron density at the neodymium(III) ion.
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M. H. V. Werts, R. H. Woudenberg, P. G. Emmerink, R. V. Gassel, J. W. Hofstraat, and J. W. Verhoeven, Angew. Chem., Int. Ed. Engl. 39, 4542 (2000).
S. Smola, N. Rusakova, and Yu. Korovin, J. Coord. Chem. 64, 863 (2011).
A. G. Martynov, E. A. Safonova, Yu. G. Gorbunova, and A. Yu. Tsivadze, Russ. J. Inorg. Chem. 55, 347 (2010).
M. P. Tsvirko, S. B. Meshkova, V. Ya. Venchikov, and D. V. Bol’shoi, Opt. Spectrosc. 87, 866 (1999).
Yu. V. Korovin, S. V. Shevchuk, V. A. Bacherikov, N. V. Rusakova, A. A. Alekseeva, and A. I. Gren’, Russ. J. Inorg. Chem. 45, 1383 (2000).
Yu. V. Korovin, Ukr. Khim. Zh. 66 (10), 101 (2000).
S. B. Meshkova, Z. M. Topilova, M. O. Lozinskii, N. V. Rusakova, and D. V. Bol’shoi, J. Anal. Chem. 52, 852 (1997).
P. C. Mehta and S. P. Tandon, J. Chem. Phys. 53, 414 (1970).
I. V. Kalinovskaya, A. Yu. Mamaev, and V. E. Karasev, Russ. J. Gen. Chem. 81, 1588 (2011).
Yu. V. Korovin, N. V. Rusakova, Z. I. Zhilina, S. V. Vodzinskii, and Yu. V. Ishkov, Ukr. Khim. Zh. 69, 732 (2002).
S. B. Meshkova, V. E. Kuz’min, I. V. Yudanova, Z. M. Topilova, and D. V. Bol’shoi, Russ. J. Inorg. Chem. 44, 1588 (1999).
I. V. Kalinovskaya, A. G. Mirochnik, and V. E. Karasev, Zh. Neorg. Khim. 36, 1778 (1991).
V. V. Korochentsev, A. V. Elovskii, V. I. Vovna, I. S. Os’mushko, A. G. Mirochnik, and I. V. Kalinovskaya, J. Struct. Chem. 58, 1120 (2017). doi 10.1134/S0022476617060087
V. V. Korochentsev, E. V. Mikhailenko, A. V. Shurygin, V. I. Vovna, I. S. Os’mushko, A. G. Mirochnik, and N. V. Petrochenkova, Russ. Chem. Bull. 66, 2081 (2017).
M. P. Seah, Surf. Interface Anal. 14, 448 (1989).
V. I. Nefedov, X-Ray Electron Spectroscopy of Chemical Compounds (Khimiya, Moscow, 1984) [in Russian].
E. Talik, M. Kruczek, H. Sakowska, Z. Ujma, M. Gala, and M. Neumann, J. Alloys Compd. 377, 259 (2004).
T. R. Cummins and R. G. Egdell, Phys. Rev. B 48, 6556 (1993).
A. Szytula and B. Penc, in Proceedings of the 16th National Symposium on Condensed Matter Physics, Sokobanja, 2004, p. 1.
N. Radutoiu and C. M. Teodorescu, Digest J. Nanomater. Biostruct. 8, 1535 (2013).
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Original Russian Text © I.V. Kalinovskaya, Yu.M. Nikolenko, 2018, published in Optika i Spektroskopiya, 2018, Vol. 125, No. 3, pp. 344–347.
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Kalinovskaya, I.V., Nikolenko, Y.M. The Fluorescent Properties and Electronic Structure of Nd(111) Complexes with Carboxylic Acids. Opt. Spectrosc. 125, 358–361 (2018). https://doi.org/10.1134/S0030400X18090126
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DOI: https://doi.org/10.1134/S0030400X18090126