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Electronic structure of europium(iii) acrylate and methacrylate: an X-ray photoelectron spectroscopy and quantum chemical study

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Abstract

The electronic structure and specific features of the nature of chemical bonding in europium acrylate and europium methacrylate were investigated by X-ray photoelectron spectroscopy (XPS) and quantum chemistry methods. The effect of the replacement of acrylic acid by methacrylic acid was also studied. The assignment of bands in the valence region XPS spectra is proposed.

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Authors and Affiliations

  1. Far Eastern Federal University, 8 ul. Sukhanova, 690950, Vladivostok, Russian Federation

    V. V. Korochentsev, E. V. Mikhailenko, A. V. Shurygin, V. I. Vovna & I. S. Os’mushko

  2. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    A. G. Mirochnik & N. V. Petrochenkova

Authors
  1. V. V. Korochentsev
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  2. E. V. Mikhailenko
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  3. A. V. Shurygin
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  4. V. I. Vovna
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  5. I. S. Os’mushko
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  6. A. G. Mirochnik
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  7. N. V. Petrochenkova
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Correspondence to V. V. Korochentsev.

Additional information

Based on the Materials of the International Conference "Advances in Synthesis and Complexation" (April 24—28, 2017, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2081—2089, November, 2017.

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Korochentsev, V.V., Mikhailenko, E.V., Shurygin, A.V. et al. Electronic structure of europium(iii) acrylate and methacrylate: an X-ray photoelectron spectroscopy and quantum chemical study. Russ Chem Bull 66, 2081–2089 (2017). https://doi.org/10.1007/s11172-017-1984-4

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  • DOI: https://doi.org/10.1007/s11172-017-1984-4

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