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Luminescence Properties of Mixed-Ligand Neodymium(III) Quinaldinates

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Abstract

Complex compounds of neodymium(III) with a quinaldic acid anion and nitrogen- and phosphorus-containing neutral ligands have been synthesized. The mixed-ligand compounds were characterized by elemental and X-ray diffraction analysis and IR spectroscopy. The thermal behavior of the obtained compounds was studied by thermal analysis in air in the temperature range 25–700°C. During the thermolysis of the complexes, the neutral ligand molecule is eliminated in one stage with an endothermic effect; the compounds are thermally stable up to 250°C. It was established by IR spectroscopy that in mixed-ligand neodymium(III) quinaldinates, the acid anion is coordinated to the central neodymium(III) ion as a bridging bidentate ligand. The luminescence properties of neodymium(III) quinaldinates were studied.

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Funding

This study was financially supported by the Ministry of Education and Science under the government contract (topic FWF no. (025)–2023-0003).

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  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    I. V. Kalinovskaya

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  1. I. V. Kalinovskaya
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Correspondence to I. V. Kalinovskaya.

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Kalinovskaya, I.V. Luminescence Properties of Mixed-Ligand Neodymium(III) Quinaldinates. Russ. J. Phys. Chem. 97, 2457–2462 (2023). https://doi.org/10.1134/S0036024423110146

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