Skip to main content
SpringerLink
Log in

The effect of solvation on spectral-luminescence properties of 2,2-difluoro-4-methylnaphto-[2,1-е]-1,3,2-dioxaborine

  • Condensed-Matter Spectroscopy
  • Published:
Optics and Spectroscopy Aims and scope Submit manuscript

Abstract

The processes of formation and dissociation of aggregates and formation of solvates of 2,2-difluoro- 4-methylnaphto-[2,1-е]-1,3,2-dioxaborine (1) with the chloroform molecule have been investigated by the methods of stationary and time-resolved spectroscopy. It has been revealed that, in the case of solutions in chloroform, a slow (within 1 h) dissociation of aggregates under the effect of solvent molecules takes place. It has been demonstrated that using chloroform as a solvent allows varying the content of luminophor aggregates in the polymeric composite and, thus, controlling the material spectral-luminescence properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives (VCH, Weinheim, 1995).

    Book  Google Scholar 

  2. A. Sakai, M. Tanaka, E. Ohta, Y. Yoshimoto, K. Mizuno, and H. Ikeda, Tetrahedron Lett. 53, 4138 (2012). doi 10.1016/j.tetlet.2012.05.122

    Article  Google Scholar 

  3. E. V. Fedorenko, B. V. Bukvetskii, A. G. Mirochnik, D.H. Shlyk, M. V. Tkacheva, and A. A. Karpenko, J. Luminesenc. 130, 756 (2010). doi 10.1016/j.jlumin. 2009.11.027

    Article  ADS  Google Scholar 

  4. A. G. Mirochnik, B. V. Bukvetskii, E. V. Fedorenko, and V. E. Karasev, Russ. Chem. Bull. 53, 291 (2004). doi 10.1023/B:RUCB.0000030800.71663.7a

    Article  Google Scholar 

  5. Y. L. Chow and C. I. Johansson, J. Phys. Chem. 99, 17558 (1995). doi 10.1021/j100049a015

    Article  Google Scholar 

  6. Y. L. Show, Z.-L. Liu, C. I. Johansson, and J.-I. Ishiyama, Chem. Eur. J. 6, 2942 (2000). doi 10.1002/1521-3765(20000818)6:16

    Article  Google Scholar 

  7. X. Liu, X. Zhang, R. Lu, P. Xue, D. Xua, and H. Zhoua, J. Mater. Chem. 21, 8756 (2011). doi 10.1039/C0JM04274A

    Article  Google Scholar 

  8. C. Qian, K. Cao, X. Liu, X. Zhang, D. Xu, P. Xue, and R. Lu, Chin. Chem. Bull. 57, 4264 (2012). doi 10.1007/s11434-012-5454-y

    Article  Google Scholar 

  9. A. G. Mirochnik, E. V. Fedorenko, and H. Shlyk, Russ. J. Phys. Chem. A 81, 1880 (2007). doi 10.1134/S0036024407110295

    Article  Google Scholar 

  10. N. D. Nguyen, G. Zhang, J. Lu, A. E. Sherman, and C. L. Fraser, J. Mater. Chem. 21, 8409 (2011). doi 10.1039/C1JM00067E

    Article  Google Scholar 

  11. G. Zhang, J. Lu, M. Sabat, and C. L. Fraser, J. Am. Chem. Soc. 132, 2160 (2010). doi 10.1021/ja9097719

    Article  Google Scholar 

  12. A. G. Mirochnik, E. V. Fedorenko, and V. E. Karasev, Russ. Chem. Bull. 57, 1190 (2008). doi 10.1007/s11172-008-0149-x

    Article  Google Scholar 

  13. A. G. Mirochnik, E. V. Gukhman, P. A. Zhihareva, and V. E. Karasev, Spectrosc. Lett. 35, 309 (2002). doi 10.1081/SL-120003815

    Article  ADS  Google Scholar 

  14. B. V. Bukvetskii, E. V. Fedorenko, A. G. Mirochnik, and V. E. Karasev, Zh. Strukt. Khim. 47, 60 (2006).

    Google Scholar 

  15. E. V. Fedorenko, A. G. Mirochnik, V. E. Karasev, and B. V. Bukvetskii, Russ. J. Phys. Chem. A 80, 1953 (2006). doi 10.1134/S0036024406120156

    Article  Google Scholar 

  16. J. A. van Allan and G. A. Reynolds, J. Heterocycl. Chem. 6 (2), 29 (1969).

    Google Scholar 

  17. A. G. Mirochnik, E. V. Fedorenko, I. G. Nagornyi, and O. A. Starovoit, Opt. Spectrosc. 122, 787 (2017). doi 10.1134/S0030400X17050149

    Article  Google Scholar 

  18. E. V. Fedorenko, A. G. Mirochnik, I. B. Lvov, and V. I. Vovna, Spectrochim. Acta, Ser. A 120, 119 (2014). doi 10.1016/j.saa.2013.10.016

    Article  Google Scholar 

  19. B. V. Bukvetskii, E. V. Fedorenko, and A. G. Mirochnik, Russ. Chem. Bull. 62, 1991 (2013). doi 10.1007/s11172-013-0289-5

    Article  Google Scholar 

  20. G. Weber, Biochem. J. 75, 335 (1960).

    Article  Google Scholar 

  21. E. V. Fedorenko, I. B. L’vov, V. I. Vovna, D. Kh. Shlyk, and A. G. Mirochnik, Russ. Chem. Bull. 59, 1041 (2010). doi 10.1007/s11172-010-0202-4

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, 690022, Russia

    A. G. Mirochnik & E. V. Fedorenko

Authors
  1. A. G. Mirochnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Fedorenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. V. Fedorenko.

Additional information

Original Russian Text © A.G. Mirochnik, E.V. Fedorenko, 2017, published in Optika i Spektroskopiya, 2017, Vol. 123, No. 3, pp. 333–336.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mirochnik, A.G., Fedorenko, E.V. The effect of solvation on spectral-luminescence properties of 2,2-difluoro-4-methylnaphto-[2,1-е]-1,3,2-dioxaborine. Opt. Spectrosc. 123, 365–368 (2017). https://doi.org/10.1134/S0030400X17090247

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0030400X17090247

Search

Navigation