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Crystal structure and luminescence properties of 4-(4-benzoyloxy-2-hydroxyphenyl)-2,2-difluoro-6-phenyl-1,3,2-dioxaborine

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Abstract

The crystal structure of 4-(4-benzoyloxy-2-hydroxyphenyl)-2,2-difluoro-6-phenyl-1,3,2-dioxaborine (1) was determined by X-ray diffraction analysis. π-π-Stacking interaction between the molecules results in joining the molecules into a three-dimensional layered framework. Luminescence of the aggregates is observed in concentrated solutions of compound 1. Two routes of excimer formation in crystal were revealed by steady-state and time-resolved luminescence spectroscopy: via excitation of single molecules and via excitation of aggregates.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    B. V. Bukvetskii, E. V. Fedorenko & A. G. Mirochnik

Authors
  1. B. V. Bukvetskii
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  2. E. V. Fedorenko
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  3. A. G. Mirochnik
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Correspondence to E. V. Fedorenko.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1991–1998, September, 2013.

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Bukvetskii, B.V., Fedorenko, E.V. & Mirochnik, A.G. Crystal structure and luminescence properties of 4-(4-benzoyloxy-2-hydroxyphenyl)-2,2-difluoro-6-phenyl-1,3,2-dioxaborine. Russ Chem Bull 62, 1991–1998 (2013). https://doi.org/10.1007/s11172-013-0289-5

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  • DOI: https://doi.org/10.1007/s11172-013-0289-5

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