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Kinetics of Chemical Reactions in Spray

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Abstract

The number of observations that demonstrate a significant effect of the size of droplets on the kinetics of chemical processes has increased with the expansion of the scope of applications of spray technology. The equations linking the concentrations of reagents, the volume of droplets, the initial composition of a solution, the composition of the gas medium, and the speed of processes are formulated within the framework of formal chemical kinetics. Using second order reactions (coupling, exchange, condensation, polymerization, and polycondensation reactions) as examples, it is shown that size kinetic effects occur when chemical processes are accompanied by changes in the droplet sizes in equilibrium with the gas medium. The results of computer simulation of condensation and polycondensation reactions are given, which reproduce size effects. Kinetic curves obtained by simulation of the polycondensation process are compared with experimental data.

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Funding

This study was carried out within the framework of State assignment for the Institute of Chemistry, Russian Academy of Sciences, with use of the equipment of Center for Collective Use Analytical Center of the Institute of Chemistry of the Russian Academy of Sciences supported by grant within program Funding the Development of Material and Technical Infrastructure of Centers for Collective Use of Scientific Equipment (unique identification code RF-2296.61321X0017, agreement no. 075-15 -2021-670).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137, Nizhny Novgorod, Russia

    V. B. Fedoseev

  2. Lobachevsky State University of Nizhny Novgorod, 603022, Nizhny Novgorod, Russia

    E. N. Fedoseeva

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  1. V. B. Fedoseev
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Correspondence to V. B. Fedoseev.

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Translated by O. Kadkin

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Fedoseev, V.B., Fedoseeva, E.N. Kinetics of Chemical Reactions in Spray. Kinet Catal 65, 85–92 (2024). https://doi.org/10.1134/S0023158423601201

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