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Formation of BI- and Polymodal Distributions and the Non-Ostwald Behavior of Disperse Systems

  • HEAT AND MASS TRANSFER IN DISPERSED AND POROUS MEDIA
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Journal of Engineering Physics and Thermophysics Aims and scope

Consideration has been given to distinctive features of the influence of the chemical and phase composition of a dispersed phase, and also of external conditions on equilibrium size distributions of evaporating solution droplets containing a nonvolatile sparingly soluble component. Equilibrium radii of droplets containing a solid phase or a supersaturated solution have been described on the basis of Kelvin and Freundlich equations and Raoult’s law. Conditions have been shown under which the non-Ostwald behavior of the dispersed phase (mass transfer from large drops to small droplets) develops. Using the model distribution as an example, the possibility of the unimodal distribution transforming into a polymodal one has been demonstrated. A maximum separation of the fractions in the distribution is attained if the partial pressure of a volatile component exceeds the pressure of a vapor above a saturated solution.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 Tropinin Str., Nizhny Novgorod, 603137, Russia

    V. B. Fedoseev

  2. Chemistry Research Institute, N. I. Lobachevskii State University of Nizhny Novgorod, 23 Gagarin Ave., Nizhny Novgorod, 603950, Russia

    E. N. Fedoseeva

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Correspondence to V. B. Fedoseev.

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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 92, No. 5, pp. 2229–2238, September–October, 2019.

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Fedoseev, V.B., Fedoseeva, E.N. Formation of BI- and Polymodal Distributions and the Non-Ostwald Behavior of Disperse Systems. J Eng Phys Thermophy 92, 1191–1200 (2019). https://doi.org/10.1007/s10891-019-02033-2

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  • DOI: https://doi.org/10.1007/s10891-019-02033-2

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