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Novel Efficient Acidic Ionic Liquid Polymer for Biodiesel Synthesis from Waste Oils

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Abstract

A highly stable acid ionic liquid polymer was prepared via the polymerization of 1-vinyl-3-(propyl-3-sulfony) imidazolium 4-styrenesulfonate. Both the cations and anions were polymerized to form the acidic ionic cross-linked polymer and the formation of cross-linked bonds prevented the loss of acidic sites. The ionic-crosslinking between cations and anions enhance the activity and stability of the ionic liquid polymer that decomposes at temperatures over 230°C. The polymer is very efficient for biodiesel synthesis from waste oils with the total yield exceeding 99% within 4 h.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Shaoxing University, 312000, Shaoxing, China

    Ruidong Wu, Haotian Ying & Xuezheng Liang

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  1. Ruidong Wu
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  2. Haotian Ying
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  3. Xuezheng Liang
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Correspondence to Xuezheng Liang.

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Abbreviations and designations: IL, ionic liquid; FFAs, free fatty acids; AIBN, azobisisobutyronitrile; GC, gas chromatography; SEM, scanning electron microscopy; BET, Brunauer–Emmett–Teller method; TG, thermogravimetric analysis; FT-IR, Fourier transform infrared spectroscopy.

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Wu, R., Ying, H. & Liang, X. Novel Efficient Acidic Ionic Liquid Polymer for Biodiesel Synthesis from Waste Oils. Kinet Catal 62, 545–550 (2021). https://doi.org/10.1134/S0023158421040121

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  • DOI: https://doi.org/10.1134/S0023158421040121

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