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FePO4/SiO2 Catalysts for Propylene Glycol Oxidation

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Abstract

FePО4/SiO2 supported catalysts with a different content of iron phosphate are prepared. The properties of the catalyst are changed by the introduction of alkali metal compounds (Na or Cs) on its surface. The samples obtained are characterized by X-ray diffraction, low-temperature nitrogen adsorption, temperatureprogrammed reduction by hydrogen, and temperature-programmed desorption of ammonia. The catalytic properties are investigated in the reaction of gas-phase propylene glycol oxidation. It is shown that the selectivity of methylglyoxal formation on the unmodified catalysts is determined by the state of the supported active component and by its reduction–oxidation ability under the action of a reaction mixture.

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References

  1. Berlowska, J., Binczarski, M., Dudkiewicz, M., Kalinowska, H., Witonska, I.A., and Stanishevsky, A., RSC Adv., 2015, vol. 5, p. 2299.

    Article  CAS  Google Scholar 

  2. Ashok, S., Raj, S.M., Rathnasingh, C., and Park, S., Appl. Microbiol. Biotechnol., 2011, vol. 90, p. 1253.

    Article  CAS  Google Scholar 

  3. Besson, M., Gallezot, P., and Pinel, C., Chem. Rev., 2014, vol. 114, no. 3, p. 1827.

    Article  CAS  Google Scholar 

  4. Pinxt, H.H.C.M., Kuster, B.F.M., and Marin, G.B., Appl. Catal., A, 2000, vol. 191, p. 45.

    Article  CAS  Google Scholar 

  5. Sugiyama, S., Tanaka, H., Bando, T., Nakagawa, K., Sotowa, K.-I., Katou, Y., Mori, T., Yasukawa, T., and Ninomiya, W., Catal. Today, 2013, vol. 203, p. 116.

    Article  CAS  Google Scholar 

  6. Chadderdon, D.J., Xin, L., Qi, J., Brady, B., Miller, J.A., Sun, K., Janik, M.J., and Li, W., ACS Catal., 2015, vol. 5, p. 6926.

    Article  CAS  Google Scholar 

  7. Feng, Y., Yin, H., Wang, A., and Xue, W., J. Catal., 2015, vol. 326, p. 26.

    Article  CAS  Google Scholar 

  8. Griffin, M.B., Rodriguez, A.A., Montemore, M.M., Monnier, J.R., Williams, C.T., and Medlin, J.W., J. Catal., 2013, vol. 307, p. 111.

    Article  CAS  Google Scholar 

  9. Williams, R.M. and Medlin, J.W., Surf. Sci., 2014, vol. 619, p. 30.

    Article  CAS  Google Scholar 

  10. Salaev, M.A., Poleshchuk, O.Kh., and Vodyankina, O.V., J. Mol. Catal. A: Chemical, 2016, vol. 417, p. 36.

    Article  CAS  Google Scholar 

  11. Ai, M., Motohashi, A., and Abe, Sh., Appl. Catal. A. General, 2003, vol. 246, p. 97.

    Article  CAS  Google Scholar 

  12. Muneyama, E., Kunishige, A., Ohdan, K., and Ai, M., J. Catal., 1996, vol. 158, p. 378.

    Article  CAS  Google Scholar 

  13. Yu, D., Wu, C., Kong, Y., Xue, N., Guo, X., and Ding, W., J. Phys. Chem., 2007, vol. 111, p. 14394.

    CAS  Google Scholar 

  14. Wang, X., Wang, Y., Tang, Q., Guo, Q., Zhang, Q., and Wan, H., J. Catal., 2003, vol. 217, p. 457.

    Article  CAS  Google Scholar 

  15. Deleplanque, J., Dubois, J.-L., Devaux, J.-F., and Ueda, W., Catal. Today, 2010, vol. 157, p. 351.

    Article  CAS  Google Scholar 

  16. Barbaux, Y., Dekiouk, M., Le Maguer, D., Gengembre, L., Huchette, D., Grimblot, J., Appl. Catal. A, 1992, vol. 90, p. 51.

    Article  CAS  Google Scholar 

  17. Agaskar, P.A., Decaul, L., and Grasselli, R.K., Catal. Lett., 1994, vol. 23, p. 339.

    Article  CAS  Google Scholar 

  18. Millet, J.M.M., Catal. Rev., 1998. V. 40. p. 1.

    Article  CAS  Google Scholar 

  19. Savel’eva, A.S., Vodyankina O.V, Russian J. Phys. Chem. A, 2014, vol. 88, no. 12, p. 2203.

    Article  Google Scholar 

  20. Nikitina, M.A. and Ivanova, I.I., ChemCatChem, 2016, vol. 8, p. 1346.

    Article  CAS  Google Scholar 

  21. Talebian-Kiakalaieh, A., Amin, N.A.S., and Hezaveh, H., Renewable Sustainable Energy Rev., 2014, vol. 40, p. 28.

    Article  CAS  Google Scholar 

  22. Zhaoa, Z., Liua, J., Duana, A., Xua, C., Kobayashib, T., and Wachs, I.E., Top. Catal., 2006, vol. 38, p. 309.

    Article  Google Scholar 

  23. Yan, B., Mahmood, A., Liang, Y., and Xu, B.-Q., Catal. Today, 2016, vol. 269, p. 65.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Tomsk State University, Tomsk, 634050, Russia

    D. Yu. Ebert, A. S. Savel’eva, N. V. Dorofeeva & O. V. Vodyankina

  2. Tomsk Polytechnic University, Tomsk, 634050, Russia

    N. V. Dorofeeva

Authors
  1. D. Yu. Ebert
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  2. A. S. Savel’eva
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  3. N. V. Dorofeeva
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  4. O. V. Vodyankina
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Corresponding author

Correspondence to D. Yu. Ebert.

Additional information

Original Russian Text © D.Yu. Ebert, A.S. Savel’eva, N.V. Dorofeeva, O.V. Vodyankina, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 6, pp. 718–723.

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Ebert, D.Y., Savel’eva, A.S., Dorofeeva, N.V. et al. FePO4/SiO2 Catalysts for Propylene Glycol Oxidation. Kinet Catal 58, 720–725 (2017). https://doi.org/10.1134/S0023158417060040

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  • DOI: https://doi.org/10.1134/S0023158417060040

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