Skip to main content
SpringerLink
Log in

Products distribution of glycerol hydrogenolysis over supported co catalysts in a liquid phase

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The products distribution of glycerol hydrogenolysis over supported Co catalysts was evaluated in a liquid phase system. The effects of support type, temperature, pressure and reaction time on the conversion of glycerol as well as yield of desired products were investigated. The preliminary results indicated that various added compounds were generated in the presence of supported Co catalysts. The type of support and the reaction temperature, pressure and time significantly affected either the glycerol conversion or the product yield. The acidity of catalyst played a more important role in the glycerol hydrogenolysis over supported Co catalysts than the specific surface and pore volume. Among the utilized supported Co catalysts, Co/γ-Al2O3 exhibited the highest acrolein yield of about 31.1% at 70.5% conversion at 200°C, 8 MPa H2 pressure and 6 h reaction time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Werpy, T. and Petersen, G., US DOE Report, 2004.

    Google Scholar 

  2. Taherzadeh, M.J., Adler, L., and Lidén, G., Enzyme Microb. Technol., 2002, vol. 31, p. 53.

    Article  CAS  Google Scholar 

  3. Wang, Z., Zhuge, J., Fang, H., and Prior, B.A., Biotechnol. Adv., 2001, vol. 19, p. 201.

    Article  CAS  Google Scholar 

  4. Hájek, M. and Skopal, F., Bioresour. Technol., 2010, vol. 101, p. 3242.

    Article  Google Scholar 

  5. Jérôme, F., Pouilloux, Y., and Barrault, J., ChemSusChem, 2008, vol. 1, p. 586.

    Article  Google Scholar 

  6. Deutsch, J., Martin, A., and Lieske, H., J. Catal., 2007, vol. 245, p. 428.

    Article  CAS  Google Scholar 

  7. Valliyappan, T., Bakhshi, N.N., and Dalai, A.K., Bioresour. Technol., 2008, vol. 99, p. 4476.

    Article  CAS  Google Scholar 

  8. Fernández, Y., Arenillas, A., Díez, M.A., Pis, J.J., and Menéndez, J.A., J. Anal. Appl. Pyrolysis, 2009, vol. 84, p. 145.

    Article  Google Scholar 

  9. Xiu, S., Shahbazi, A., Shirley, V., Mims, M.R., and Wallace, C.W., J. Anal. Appl. Pyrolysis, 2010, vol. 87, p. 194.

    Article  CAS  Google Scholar 

  10. Skoulou, V.K., Manara, P., and Zabaniotou, A.A., J. Anal. Appl. Pyrolysis, 2012, vol. 97, p. 198.

    Article  CAS  Google Scholar 

  11. May, A., Salvadó, J., Torras, C., and Montané, D., Chem. Eng. J., 2010, vol. 160, p. 751.

    Article  CAS  Google Scholar 

  12. Atong, D., Pechyen, C., Aht-Ong, D., and Sricharoenchaikul, V., Appl. Clay Sci., 2011, vol. 53, p. 244.

    Article  CAS  Google Scholar 

  13. Wei, L., Pordesimo, L.O., Haryanto, A., and Wooten, J., Bioresour. Technol., 2011, vol. 102, p. 6266.

    Article  CAS  Google Scholar 

  14. Guo, S., Guo, L., Cao, C., Yin, J., Lu, Y., and Zhang, X., Int. J. Hydrogen Energy, 2012, vol. 37, p. 5559.

    Article  CAS  Google Scholar 

  15. Kimura, H., Tsuto, K., Wakisaka, T., Kazumi, Y., and Inaya, Y., Appl. Catal., A, 1993, vol. 96, p. 217.

    Article  CAS  Google Scholar 

  16. Porta, F. and Prati, L., J. Catal., 2004, vol. 224, p. 397.

    Article  CAS  Google Scholar 

  17. Gil, S., Marchena, M., Sánchez-Silva, L., Romero, A., Sánchez, P., and Valverde, J.L., Chem. Eng. J., 2011, vol. 178, p. 423.

    Article  CAS  Google Scholar 

  18. Liang, D., Gao, J., Sun, H., Chen, P., Hou, Z., and Zheng, X., Appl. Catal., vol. 106, p. 423.

  19. Rodrigues, E.G., Carabineiro, S.A.C., Delgado, J.J., Chen, X., Pereira, M.F.R., and Órfãpfão, J.J.M., J. Catal., 2012, vol. 285, p. 83.

    Article  CAS  Google Scholar 

  20. Pasteris, S.E. and Strasser de Saad, A.M., Food Microbiol., 2005, vol. 22, p. 399.

    Article  CAS  Google Scholar 

  21. André, A., Diamantopoulou, P., Philippoussis, A., Sarris, D., Komaitis, M., and Papanikolaou, S., Ind. Crops Prod., 2010, vol. 31, p. 407.

    Article  Google Scholar 

  22. Chatzifragkou, A., Makri, A., Belka, A., Bellou, S., Mavrou, M., Mastoridou, M., Mystrioti, P., Onjaro, G., Aggelis, G., and Papanikolaou, S., Energy, 2011, vol. 36, p. 1097.

    Article  CAS  Google Scholar 

  23. Metsoviti, M., Paraskevaidi, K., Koutinas, A., Zeng, A., and Papanikolaou, S., Proc. Biochem., 2012, vol. 47, p. 1872.

    Article  CAS  Google Scholar 

  24. Liao, X., Zhu, Y., Wang, S., and Li, Y., Fuel Process. Technol., 2009, vol. 90, p. 988.

    Article  CAS  Google Scholar 

  25. Zhou, L., Al-Zaini, E., and Adesina, A.A., Fuel, 2013, vol. 103, p. 67.

    Google Scholar 

  26. Melero, J.A., Vicente, G., Paniagua, M., Morales, G., and Muñoz, P., Bioresour. Technol., 2012, vol. 103, p. 142.

    Article  CAS  Google Scholar 

  27. Duque, J.A.P., Dissertation, Manizales: National University of Colombia, 2011.

  28. Balaraju, M., Rekha, V., Sai Prasad, P.S., Prabhavathi Devi, B.L.A., Prasad, R.B.N., and Lingaiah, N., Appl. Catal., A, 2009, vol. 354, p. 82.

    Article  CAS  Google Scholar 

  29. Huang, L., Zhu, Y., Zheng, H., Ding, G., and Li, Y., Catal. Lett., 2009, vol. 131, p. 312.

    Article  CAS  Google Scholar 

  30. Wang, K., Hawley, M.C., and Furney, T.D., Chem. Eng. Sci., 2003, vol. 58, p. 4271.

    Article  CAS  Google Scholar 

  31. Perosa, A. and Tundo, P., Ind. Eng. Chem. Res., 2005, vol. 44, p. 8535.

    Article  CAS  Google Scholar 

  32. Hoşgün, H.L., Yıldız, M., and Gerşel, H.F., Ind. Eng. Chem. Res., 2012, vol. 51, p. 3863.

    Article  Google Scholar 

  33. Liang, C., Ma, Z., Ding, L., and Qiu, J., Catal. Lett., 2009, vol. 130, p. 169.

    Article  CAS  Google Scholar 

  34. Mane, R.B. and Rode, C.V., Org. Process Res. Dev., 2012, vol. 16, p. 1043.

    Article  CAS  Google Scholar 

  35. Mane, R.B., Ghalwadkar, A.A., Hengne, A.M., Suryawanshi, Y.R., and Rode, C.V., Catal. Today, 2011, vol. 164, p. 447.

    Article  CAS  Google Scholar 

  36. Wang, S., Zhang, Y., and Liu, H., Chem. Asian, J., 2010, vol. 5, p. 1100.

    Article  CAS  Google Scholar 

  37. Bienholz, A., Blume, R., Knop-Gericke, A., Girgsdies, F., Behrens, M., and Claus, P., J. Phys. Chem. C, 2011, vol. 115, p. 999.

    Article  CAS  Google Scholar 

  38. Guo, X., Li, Y., Shi, R., Liu, Q., Zhan, E., and Shen, W., Appl. Catal., A, 2009, vol. 371, p. 108.

    Article  CAS  Google Scholar 

  39. Dasari, M.A., Kiatsimkul, P., Sutterlin, W.R., and Suppes, G.J., Appl. Catal., A, 2005, vol. 281, p. 225.

    Article  CAS  Google Scholar 

  40. Gong, L., Lu, Y., Ding, Y., Lin, R., Li, J., Dong, W., Wang, T., and Chen, W., Appl. Catal., A, 2010, vol. 390, p. 119.

    Article  CAS  Google Scholar 

  41. Nakagawa, Y. and Tomishige, K., Catal. Sci. Technol., 2011, vol. 1, p. 179.

    Article  CAS  Google Scholar 

  42. Barbelli, M.L., Santori, G.F., and Nichio, N.N., Bioresour. Technol., 2012, vol. 111, p. 500.

    Article  CAS  Google Scholar 

  43. Ma, L. and He, D., Catal. Today, 2010, vol. 149, p. 148.

    Article  CAS  Google Scholar 

  44. Lan, M.A., Yuming, L.I., and Dehua, H.E., Chin. J. Catal., 2011, vol. 32, p. 872.

    Article  Google Scholar 

  45. Kusunoki, Y., Miyazawa, T., Kunimori, K., and Tomishige, K., Catal. Commun., 2005, vol. 6, p. 645.

    Article  CAS  Google Scholar 

  46. Musolino, M.G., Scarpino, L.A., Mauriello, F., and Pietropaolo, R., Green Chem., 2009, vol. 11, p. 1511.

    Article  CAS  Google Scholar 

  47. Musolino, M.G., Scarpino, L.A., Mauriello, F., and Pietropaolo, R., ChemSusChem, 2011, vol. 4, p. 1143.

    Article  CAS  Google Scholar 

  48. Nakagawa, Y., Ning, X., Amada, Y., and Tomishige, K., Appl. Catal., A, 2012, vol. 8, p. 128.

    Article  Google Scholar 

  49. Amada, Y., Shinmi, Y., Koso, S., Kubota, T., Nakagawa, Y., and Tomishige, K., Appl. Catal., B, 2011, vol. 105, p. 117.

    Article  CAS  Google Scholar 

  50. Nakagawa, Y., Shinmi, Y., Koso, S., and Tomishige, K., J. Catal., 2010, vol. 272, p. 191.

    Article  CAS  Google Scholar 

  51. Masel, R.I., Chemical Kinetics and Catalysis, New York: Wiley, 2001.

    Google Scholar 

  52. Páramo Garcia, A., Esthela Ramos, R., del Angel, G., Navarrete, J., and Contreras Cesar, A. doi10.2240/azojomo0261. http://www.azom.com/article.aspx?ArticleID=4035

  53. Fischer, A., Maciejewski, M., Búrgi, T., Mallat, T., and Baiker, A., J. Catal., 1999, vol. 183, p. 373.

    Article  CAS  Google Scholar 

  54. Bhagiyalakshmi, M., Yun, L.J., Anuradha, R., and Jang, H.T., J. Hazard. Mater., 2010, vol. 175, p. 928.

    Article  CAS  Google Scholar 

  55. Escobar, J., Barrera, M.C., Reyes, J.A., Toledo, J.A., Santes, V., and Colin, J.A., J. Mol. Catal. A: Chem., 2008, vol. 287, p. 33.

    Article  CAS  Google Scholar 

  56. Garg, S., Soni, K., Kumaran, G.M., Kumar, M., Gupta, J.K., Sharma, L.D., and Dhar, G.M., Catal. Today, 2008, vol. 130, p. 302.

    Article  CAS  Google Scholar 

  57. Atia, H., Armbruster, U., and Martin, A., J. Catal., 2008, vol. 258, p. 71.

    Article  CAS  Google Scholar 

  58. Kongjao, S., Damronglerd, S., and Hunsom, M., J. Appl. Electrochem., 2011, vol. 41, p. 215.

    Article  CAS  Google Scholar 

  59. Zheng, Y., Chen, X., and Shen, Y., Chem. Rev., 2008, vol. 108, p. 5253.

    Article  CAS  Google Scholar 

  60. Lahr, D.G. and Shanks, B.H., J. Catal., 2005, vol. 232, no. 2, p. 386.

    Article  CAS  Google Scholar 

  61. Torres, A., Roy, D., Subramaniam, B., and Chaudhari, R.V., Ind. Eng. Chem. Res., 2010, vol. 49, p. 10826.

    Article  CAS  Google Scholar 

  62. Vasiliadou, E.S. and Lemonidou, A.A., Chem. Eng. J., 2013, vol. 231, p. 103.

    Article  CAS  Google Scholar 

  63. Zhou, Z., Li, X., Zeng, T., Hong, W., Cheng, H., and Yuan, W., Chin. J. Chem. Eng., 2010, vol. 18, no. 3, p. 384.

    Article  CAS  Google Scholar 

  64. Miyazawa, T., Kusunoki, Y., Kunimori, K., and Tomishige, K., J. Catal., 2006, vol. 240, p. 213.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Fuels Research Center, Department of Chemical Technology, Faculty of Science, Chulalongkorn University, Bangkok, Thailand

    S. Raksaphort & M. Hunsom

  2. Department of Chemical Engineering, Mahanakorn University of Technology, Bangkok, Thailand

    S. Pengpanich

  3. Center of Excellence on Petrochemical and Materials Technology (PETRO-MAT), Chulalongkorn University, Bangkok, Thailand

    M. Hunsom

Authors
  1. S. Raksaphort
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Pengpanich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Hunsom
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Raksaphort.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Raksaphort, S., Pengpanich, S. & Hunsom, M. Products distribution of glycerol hydrogenolysis over supported co catalysts in a liquid phase. Kinet Catal 55, 434–445 (2014). https://doi.org/10.1134/S0023158414040132

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158414040132

Keywords

Search

Navigation